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@ARTICLE{Fedosov:20485,
author = {Fedosov, D.A. and Singh, S.P. and Chatterji, A. and
Winkler, R.G. and Gompper, G.},
title = {{S}emidilute solutions of ultra-soft colloids under shear
flow},
journal = {Soft matter},
volume = {8},
issn = {1744-683X},
address = {Cambridge},
publisher = {Royal Society of Chemistry (RSC)},
reportid = {PreJuSER-20485},
pages = {4109 - 4120},
year = {2012},
note = {We thank J. K. G. Dhont, J. Stellbrink, D. Richter, M.
Ripoll (Julich), and D. Vlassopoulos (FORTH Crete) for
stimulating discussions. Financial support by the Deutsche
Forschungsgemeinschaft (DFG) through the Collaborative
Research Center "Physics of Colloidal Dispersions in
External Fields" (SFB TR6), and by the EU through the
Collaborative Research Project "NanoDirect"
(NMP4-SL-2008-213948) is gratefully acknowledged. D. A. F.
acknowledges funding by the Humboldt Foundation through a
postdoctoral fellowship.},
abstract = {We study semidilute star-polymer solutions under shear flow
by hybrid mesoscale simulations. Hydrodynamic interactions
are modeled by two particle-based simulation techniques,
multiparticle collision dynamics (MPC) and dissipative
particle dynamics (DPD). Star polymers are considered as a
paradigmatic model for ultra-soft colloids with variable
softness. The influence of concentration and shear rate on
their structural and rheological properties is investigated.
Under flow, a star polymer elongates and displays a
well-defined alignment angle with respect to the flow
direction. Moreover, the structural and rheological
properties exhibit a universal behavior as a function of a
concentration-dependent Weissenberg number for various
concentrations at a given arm length. The rheological
properties are characterized by the shear viscosity and the
normal-stress coefficients. In dilute solution, the
zero-shear viscosity follows the Einstein relation with an
effective radius given by the hydrodynamic radius of a star
polymer. At high shear rates, the solutions exhibit
shear-thinning behavior, where the viscosity decreases
faster with increasing shear rate at higher concentrations.
We demonstrate that the results obtained from MPC and DPD
agree in all scaling properties, with minor quantitative
deviations in the numerical values.},
keywords = {J (WoSType)},
cin = {IAS-2 / ICS-2},
ddc = {530},
cid = {I:(DE-Juel1)IAS-2-20090406 / I:(DE-Juel1)ICS-2-20110106},
pnm = {BioSoft: Makromolekulare Systeme und biologische
Informationsverarbeitung},
pid = {G:(DE-Juel1)FUEK505},
shelfmark = {Chemistry, Physical / Materials Science, Multidisciplinary
/ Physics, Multidisciplinary / Polymer Science},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000301801100011},
doi = {10.1039/c2sm07009j},
url = {https://juser.fz-juelich.de/record/20485},
}