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000020700 084__ $$2WoS$$aChemistry, Multidisciplinary
000020700 1001_ $$0P:(DE-HGF)0$$aKleshchanok, D.$$b0
000020700 245__ $$aLyotropic Smectic B Phase Formed in Suspensions of Charged Colloidal Platelets
000020700 260__ $$aWashington, DC$$bAmerican Chemical Society$$c2012
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000020700 520__ $$aHere, we present the first observation of a smectic B (Sm(B)) phase in a system of charged colloidal gibbsite platelets suspended in dimethyl sulfoxide (DMSO). The use of DMSO, a polar aprotic solvent, leads to a long range of the electrostatic Coulomb repulsion between platelets. We believe this to be responsible for the formation of the layered liquid crystalline phase consisting of hexagonally ordered particles, that is, the Sm(B) phase. We support our finding by high-resolution X-ray scattering experiments, which additionally indicate a high degree of ordering in the Sm(B) phase.
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