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@ARTICLE{Puschnig:20701,
author = {Puschnig, P. and Reinisch, E.-M. and Ules, T. and Koller,
G. and Soubatch, S. and Ostler, M. and Romaner, L. and
Tautz, F.S. and Ambrosch-Draxl, C. and Ramsey, M.G.},
title = {{O}rbital tomography: {D}econvoluting photoemission spectra
of organic molecules},
journal = {Physical review / B},
volume = {84},
number = {23},
issn = {1098-0121},
address = {College Park, Md.},
publisher = {APS},
reportid = {PreJuSER-20701},
pages = {235427},
year = {2011},
note = {We acknowledge financial support from the Austrian Science
Fund (FWF), projects S97-04 and S97-14 and P21330-N20 and
P23190-N16, and from the Deutsche Forschungsgemeinschaft,
project TA-244. We further acknowledge the
Helmholtz-Zentrum-Berlin, Electron storage ring BESSY II for
provision of synchrotron radiation at beamline U125/2-SGM,
and in particular we thank Dr. Christian
Schussler-Langeheine for assistance. We would also like to
thank Prof. Falko P. Netzer and Prof. Thomas Seyller for
discussions. The research leading to these results has
received funding from the European Community's Seventh
Framework Programme (FP7/2007-2013) under grant agreement
number 226716.},
abstract = {We study the interface of an organic monolayer with a
metallic surface, i.e., PTCDA
(3,4,9,10-perylene-tetracarboxylic-dianhydride) on Ag(110),
by means of angle-resolved photoemission spectroscopy
(ARPES) and ab initio electronic structure calculations. We
present a tomographic method that uses the energy and
momentum dependence of ARPES data to deconvolute spectra
into individual orbital contributions beyond the limits of
energy resolution. This provides an orbital-by-orbital
characterization of large adsorbate systems without the need
to invoke a sophisticated theory of photoemission, allowing
us to directly estimate the effects of bonding on individual
orbitals. Moreover, these experimental data serve as a most
stringent test necessary for the further development of ab
initio electronic structure theory.},
keywords = {J (WoSType)},
cin = {PGI-3 / JARA-FIT},
ddc = {530},
cid = {I:(DE-Juel1)PGI-3-20110106 / $I:(DE-82)080009_20140620$},
pnm = {Grundlagen für zukünftige Informationstechnologien /
ELISA - European Light Sources Activities - Synchrotrons and
Free Electron Lasers (226716)},
pid = {G:(DE-Juel1)FUEK412 / G:(EU-Grant)226716},
shelfmark = {Physics, Condensed Matter},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000298115400006},
doi = {10.1103/PhysRevB.84.235427},
url = {https://juser.fz-juelich.de/record/20701},
}