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@ARTICLE{Mauer:21054,
      author       = {Mauer, G. and Sebold, D. and Vaßen, R. and Stöver, D.},
      title        = {{I}mproving {A}tmospheric {P}lasma {S}praying of
                      {Z}irconate {T}hermal {B}arrier {C}oatings {B}ased on
                      {P}article {D}iagnostics},
      journal      = {Journal of thermal spray technology},
      volume       = {21},
      number       = {3-4},
      issn         = {1059-9630},
      address      = {Boston, Mass.},
      publisher    = {Springer},
      reportid     = {PreJuSER-21054},
      pages        = {363-371},
      year         = {2012},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {Lanthanum zirconate (La2Zr2O7) has been proposed as a
                      promising material for thermal barrier coatings. During
                      atmospheric plasma spraying (APS) of La2Zr2O7 a considerable
                      amount of La2O3 can evaporate in the plasma flame, resulting
                      in a non-stoichiometric coating. As indicated in the phase
                      diagram of the La2O3-ZrO2 system, in the composition range
                      of pyrochlore structure, the stoichiometric La2Zr2O7 has the
                      highest melting point and other compositions are eutectic.
                      APS experiments were performed with a TriplexPro (TM)-200
                      plasma torch at different power levels to achieve different
                      degrees of evaporation and thus stoichiometry. For
                      comparison, some investigations on gadolinium zirconate
                      (Gd2Zr2O7) were included, which is less prone to evaporation
                      and formation of non-stoichiometry. Particle temperature
                      distributions were measured by the DPV-2000 diagnostic
                      system. In these distributions, characteristic peaks were
                      detected at specific torch input powers indicating
                      evaporation and solidification processes. Based on this,
                      process parameters can be defined to provide stoichiometric
                      coatings that show good thermal cycling performance.},
      keywords     = {J (WoSType)},
      cin          = {IEK-1},
      ddc          = {670},
      cid          = {I:(DE-Juel1)IEK-1-20101013},
      pnm          = {Rationelle Energieumwandlung},
      pid          = {G:(DE-Juel1)FUEK402},
      shelfmark    = {Materials Science, Coatings $\&$ Films},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000303472800002},
      doi          = {10.1007/s11666-011-9706-1},
      url          = {https://juser.fz-juelich.de/record/21054},
}