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000021137 084__ $$2WoS$$aMaterials Science, Multidisciplinary
000021137 084__ $$2WoS$$aPhysics, Applied
000021137 084__ $$2WoS$$aPhysics, Condensed Matter
000021137 1001_ $$0P:(DE-Juel1)VDB72190$$aSpelthahn, H.$$b0$$uFZJ
000021137 245__ $$aDevelopment of a thin-film sensor array for analytical monitoring of heavy metals in aqueous solutions
000021137 260__ $$aWeinheim$$bWiley-VCH$$c2012
000021137 300__ $$a885 - 891
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000021137 440_0 $$04913$$aPhysica Status Solidi A$$v209$$x0031-8965$$y5
000021137 500__ $$3POF3_Assignment on 2016-02-29
000021137 500__ $$aThe authors thank the joint program between the Federal Ministry for Education and Research (BMBF, Germany) and FASIE (Russia) within the project "Multimodal sensors for control of ecological safety of aqueous media in industrial environment'' for financial support of these studies.
000021137 520__ $$aIn industrial processes there is a variety of heavy metals (e.g., copper, zinc, cadmium, and lead) in use for wires, coatings, paints, alloys, batteries, etc. Since the application of these transition metals for industry is inevitable, it is a vital task to develop proper analytical techniques for their monitoring at low activity levels, especially because most of these elements are acutely toxic for biological organisms. The determination of ions in solution by means of a simple and inexpensive sensor array is, therefore, a promising task. In this work, a sensor array with heavy metal-sensitive chalcogenide glass membranes for the simultaneous detection of the four ions Ag+, Cu2+, Cd2+, and Pb2+ in solution is realized. The results of the physical characterization by means of microscopy, profilometry, Rutherford backscattering spectroscopy (RBS), and scanning electron microscopy (SEM) as well as the electrochemical characterization by means of potentiometric measurements are presented. Additionally, the possibility to expand the sensor array by polymeric sensor membranes is discussed. (c) 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
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000021137 65320 $$2Author$$achalcogenide glass
000021137 65320 $$2Author$$aion-selective microelectrodes
000021137 65320 $$2Author$$aPLD
000021137 65320 $$2Author$$apolymeric sensor membrane
000021137 65320 $$2Author$$asensor array
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000021137 7001_ $$0P:(DE-HGF)0$$aKirsanov, D.$$b1
000021137 7001_ $$0P:(DE-HGF)0$$aLegin, A.$$b2
000021137 7001_ $$0P:(DE-HGF)0$$aOsterrath, T.$$b3
000021137 7001_ $$0P:(DE-Juel1)128631$$aSchubert, J.$$b4$$uFZJ
000021137 7001_ $$0P:(DE-Juel1)128648$$aZander, W.$$b5$$uFZJ
000021137 7001_ $$0P:(DE-Juel1)128727$$aSchöning, M.J.$$b6$$uFZJ
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000021137 8567_ $$uhttp://dx.doi.org/10.1002/pssa.201100733
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