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000021154 084__ $$2WoS$$aChemistry, Multidisciplinary
000021154 1001_ $$0P:(DE-Juel1)VDB91881$$aReigh, S.Y.$$b0$$uFZJ
000021154 245__ $$aDirect Calculation Method for Excited-state Diffusion-influenced Reversible Reactions with an External Field
000021154 260__ $$aSeoul$$bSoc.$$c2012
000021154 300__ $$a1015
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000021154 440_0 $$025924$$aBulletin of the Korean Chemical Society$$v33$$y3
000021154 500__ $$aS. Y. Reigh thanks K. J. Shin for his support and discussions. H. Kim was supported by research funds from Dong-A University.
000021154 520__ $$aThe direct calculation method is generalized to the excited-state diffusion-influenced reversible reaction of a neutral and a charged particle under an external field with two different lifetimes and quenching in three dimensions. The present method provides an alternative way to calculate the binding probability density functions and the survival probabilities from the corresponding irreversible results. The solutions are obtained as the series solutions by the diagonal approximation due to the anisotropy of the unidirectional external field. The numerical results are found to be in good agreement with those of the previous study [S. Y. Reigh et al. J. Chem. Phys. 132,164112 (2010)] within a weak field limit. The solutions of two approaches show qualitatively the same overall behavior including the power laws at long times.
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000021154 65320 $$2Author$$aReversible reaction
000021154 65320 $$2Author$$aExternal field
000021154 65320 $$2Author$$aReaction-diffusion systems
000021154 65320 $$2Author$$aExcited state reaction
000021154 65320 $$2Author$$aAnisotropy
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000021154 7001_ $$0P:(DE-Juel1)VDB753$$aKim, H.$$b1$$uFZJ
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