TY  - JOUR
AU  - Sang, X.F.
AU  - Gensch, I.
AU  - Laumer, W.
AU  - Kammer, B.
AU  - Chan, C.Y.
AU  - Engling, G.
AU  - Wahner, A.
AU  - Wissel, H.
AU  - Kiendler-Scharr, A.
TI  - Stable carbon isotope ratio analysis of anhydrosugars in biomass burning aerosol particles from source samples
JO  - Environmental Science & Technology
VL  - 46
SN  - 0013-936X
CY  - Columbus, Ohio
PB  - American Chemical Society
M1  - PreJuSER-21190
SP  - 3312 - 3318
PY  - 2012
N1  - Record converted from VDB: 12.11.2012
AB  - A new method for stable carbon isotope ratio analysis of anhydrosugars from biomass burning aerosol particle source filter samples was developed by employing Thermal Desorption--2 Dimensional Gas Chromatography--Isotope Ratio Mass Spectrometry (TD-2DGC-IRMS). Compound specific isotopic measurements of levoglucosan, mannosan, and galactosan performed by TD-2DGC-IRMS in a standard mixture show good agreement with isotopic measurements of the bulk anhydrosugars, carried out by Elemental Analyzer--Isotope Ratio Mass Spectrometry (EA-IRMS). The established method was applied to determine the isotope ratios of levoglucosan, mannosan, and galactosan from source samples collected during combustion of hard wood, softwood, and crop residues. δ(13)C values of levoglucosan were found to vary between -25.6 and -22.2‰, being higher in the case of softwood. Mannosan and galactosan were detected only in the softwood samples showing isotope ratios of -23.5‰ (mannosan) and -25.7‰ (galactosan). The isotopic composition of holocellulose in the plant material used for combustion experiments was determined with δ(13)C values between -28.5 and -23.7‰. The difference in δ(13)C of levoglucosan in biomass burning aerosol particles compared to the parent fuel holocellulose was found to be -1.89 (±0.37)‰ for the investigated biomass fuels. Compound specific δ(13)C measurements of anhydrosugars should contribute to an improved source apportionment.
KW  - Aerosols
KW  - Air Pollutants: analysis
KW  - Angiosperms
KW  - Biomass
KW  - Carbon Isotopes: analysis
KW  - Gymnosperms
KW  - Hexoses: analysis
KW  - Hot Temperature
KW  - Particulate Matter: analysis
KW  - Aerosols (NLM Chemicals)
KW  - Air Pollutants (NLM Chemicals)
KW  - Carbon Isotopes (NLM Chemicals)
KW  - Hexoses (NLM Chemicals)
KW  - Particulate Matter (NLM Chemicals)
LB  - PUB:(DE-HGF)16
C6  - pmid:22313249
UR  - <Go to ISI:>//WOS:000301630200036
DO  - DOI:10.1021/es204094v
UR  - https://juser.fz-juelich.de/record/21190
ER  -