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000021203 084__ $$2WoS$$aEnvironmental Sciences
000021203 1001_ $$0P:(DE-Juel1)129475$$aJablonowski, N.D.$$b0$$uFZJ
000021203 245__ $$aLong-term persistence of various 14C-labeled pesticides in soils
000021203 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2012
000021203 300__ $$a29 - 36
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000021203 440_0 $$08083$$aEnvironmental Pollution$$v168$$x0269-7491
000021203 500__ $$aSincere thanks are due to Bayer Crop Science for the initial support and funding of the lysimeter studies and for the chemical standards. Help and assistance in the laboratory from Martina Krause and Ulrike Langen is highly appreciated. We are grateful for the maintenance of the outdoor lysimeters by the technical staff of the Agrosphere institute. The entire experiment was conducted at the Agrosphere institute, IBG-3.
000021203 520__ $$aThe fate of the 14C-labeled herbicides ethidimuron (ETD), methabenzthiazuron (MBT), and the fungicide anilazine (ANI) in soils was evaluated after long-term aging (9-17 years) in field based lysimeters subject to crop rotation. Analysis of residual 14C activity in the soils revealed 19% (ETD soil; 0-10 cm depth), 35% (MBT soil; 0-30), and 43% (ANI soil; 0-30) of the total initially applied. Accelerated solvent extraction yielded 90% (ETD soil), 26% (MBT soil), and 41% (ANI soil) of residual pesticide 14C activity in the samples. LC-MS/MS analysis revealed the parent compounds ETD and MBT, accounting for 3% and 2% of applied active ingredient in the soil layer, as well as dihydroxy-anilazine as the primary ANI metabolite. The results for ETD and MBT were matching with values obtained from samples of a 12 year old field plot experiment. The data demonstrate the long-term persistence of these pesticides in soils based on outdoor trials.
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000021203 65320 $$2Author$$aEthidimuron
000021203 65320 $$2Author$$aMethabenzthiazuron
000021203 65320 $$2Author$$aAnilazine
000021203 65320 $$2Author$$aPersistence
000021203 65320 $$2Author$$aBound residues
000021203 650_2 $$2MeSH$$aBenzothiazoles: analysis
000021203 650_2 $$2MeSH$$aCarbon Radioisotopes
000021203 650_2 $$2MeSH$$aEnvironmental Monitoring
000021203 650_2 $$2MeSH$$aFungicides, Industrial: analysis
000021203 650_2 $$2MeSH$$aHerbicides: analysis
000021203 650_2 $$2MeSH$$aMethylurea Compounds: analysis
000021203 650_2 $$2MeSH$$aModels, Chemical
000021203 650_2 $$2MeSH$$aSoil: chemistry
000021203 650_2 $$2MeSH$$aSoil Pollutants: analysis
000021203 650_2 $$2MeSH$$aTriazines: analysis
000021203 650_7 $$00$$2NLM Chemicals$$aBenzothiazoles
000021203 650_7 $$00$$2NLM Chemicals$$aCarbon Radioisotopes
000021203 650_7 $$00$$2NLM Chemicals$$aFungicides, Industrial
000021203 650_7 $$00$$2NLM Chemicals$$aHerbicides
000021203 650_7 $$00$$2NLM Chemicals$$aMethylurea Compounds
000021203 650_7 $$00$$2NLM Chemicals$$aSoil
000021203 650_7 $$00$$2NLM Chemicals$$aSoil Pollutants
000021203 650_7 $$00$$2NLM Chemicals$$aTriazines
000021203 650_7 $$00$$2NLM Chemicals$$aethidimuron
000021203 650_7 $$0101-05-3$$2NLM Chemicals$$adyrene
000021203 650_7 $$018691-97-9$$2NLM Chemicals$$amethabenzthiazuron
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000021203 7001_ $$0P:(DE-HGF)0$$aLinden, A.$$b1
000021203 7001_ $$0P:(DE-Juel1)VDB4032$$aKöppchen, S.$$b2$$uFZJ
000021203 7001_ $$0P:(DE-Juel1)129410$$aThiele, B.$$b3$$uFZJ
000021203 7001_ $$0P:(DE-Juel1)129471$$aHofmann, D.$$b4$$uFZJ
000021203 7001_ $$0P:(DE-Juel1)VDB1076$$aMittelstaedt, W.$$b5$$uFZJ
000021203 7001_ $$0P:(DE-Juel1)VDB2346$$aPütz, T.$$b6$$uFZJ
000021203 7001_ $$0P:(DE-Juel1)VDB202$$aBurauel, P.$$b7$$uFZJ
000021203 773__ $$0PERI:(DE-600)2013037-5$$a10.1016/j.envpol.2012.04.022$$gVol. 168, p. 29 - 36$$p29 - 36$$q168<29 - 36$$tEnvironmental pollution$$v168$$x0269-7491$$y2012
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