Hauptseite > Publikationsdatenbank > Long-term persistence of various 14C-labeled pesticides in soils > print

001     21203
005     20200423203229.0
024 7 _ |a pmid:22591787
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024 7 _ |a 10.1016/j.envpol.2012.04.022
|2 DOI
024 7 _ |a WOS:000306034900005
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024 7 _ |a 2128/7470
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037 _ _ |a PreJuSER-21203
041 _ _ |a eng
082 _ _ |a 333.7
084 _ _ |2 WoS
|a Environmental Sciences
100 1 _ |a Jablonowski, N.D.
|b 0
|u FZJ
|0 P:(DE-Juel1)129475
245 _ _ |a Long-term persistence of various 14C-labeled pesticides in soils
260 _ _ |a Amsterdam [u.a.]
|b Elsevier Science
|c 2012
300 _ _ |a 29 - 36
336 7 _ |a Journal Article
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336 7 _ |a Journal Article
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336 7 _ |a JOURNAL_ARTICLE
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336 7 _ |a article
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440 _ 0 |a Environmental Pollution
|x 0269-7491
|0 8083
|v 168
500 _ _ |a Sincere thanks are due to Bayer Crop Science for the initial support and funding of the lysimeter studies and for the chemical standards. Help and assistance in the laboratory from Martina Krause and Ulrike Langen is highly appreciated. We are grateful for the maintenance of the outdoor lysimeters by the technical staff of the Agrosphere institute. The entire experiment was conducted at the Agrosphere institute, IBG-3.
520 _ _ |a The fate of the 14C-labeled herbicides ethidimuron (ETD), methabenzthiazuron (MBT), and the fungicide anilazine (ANI) in soils was evaluated after long-term aging (9-17 years) in field based lysimeters subject to crop rotation. Analysis of residual 14C activity in the soils revealed 19% (ETD soil; 0-10 cm depth), 35% (MBT soil; 0-30), and 43% (ANI soil; 0-30) of the total initially applied. Accelerated solvent extraction yielded 90% (ETD soil), 26% (MBT soil), and 41% (ANI soil) of residual pesticide 14C activity in the samples. LC-MS/MS analysis revealed the parent compounds ETD and MBT, accounting for 3% and 2% of applied active ingredient in the soil layer, as well as dihydroxy-anilazine as the primary ANI metabolite. The results for ETD and MBT were matching with values obtained from samples of a 12 year old field plot experiment. The data demonstrate the long-term persistence of these pesticides in soils based on outdoor trials.
536 _ _ |a Atmosphäre und Klima
|c P23
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588 _ _ |a Dataset connected to Web of Science, Pubmed
650 _ 2 |2 MeSH
|a Benzothiazoles: analysis
650 _ 2 |2 MeSH
|a Carbon Radioisotopes
650 _ 2 |2 MeSH
|a Environmental Monitoring
650 _ 2 |2 MeSH
|a Fungicides, Industrial: analysis
650 _ 2 |2 MeSH
|a Herbicides: analysis
650 _ 2 |2 MeSH
|a Methylurea Compounds: analysis
650 _ 2 |2 MeSH
|a Models, Chemical
650 _ 2 |2 MeSH
|a Soil: chemistry
650 _ 2 |2 MeSH
|a Soil Pollutants: analysis
650 _ 2 |2 MeSH
|a Triazines: analysis
650 _ 7 |0 0
|2 NLM Chemicals
|a Benzothiazoles
650 _ 7 |0 0
|2 NLM Chemicals
|a Carbon Radioisotopes
650 _ 7 |0 0
|2 NLM Chemicals
|a Fungicides, Industrial
650 _ 7 |0 0
|2 NLM Chemicals
|a Herbicides
650 _ 7 |0 0
|2 NLM Chemicals
|a Methylurea Compounds
650 _ 7 |0 0
|2 NLM Chemicals
|a Soil
650 _ 7 |0 0
|2 NLM Chemicals
|a Soil Pollutants
650 _ 7 |0 0
|2 NLM Chemicals
|a Triazines
650 _ 7 |0 0
|2 NLM Chemicals
|a ethidimuron
650 _ 7 |0 101-05-3
|2 NLM Chemicals
|a dyrene
650 _ 7 |0 18691-97-9
|2 NLM Chemicals
|a methabenzthiazuron
650 _ 7 |a J
|2 WoSType
653 2 0 |2 Author
|a Ethidimuron
653 2 0 |2 Author
|a Methabenzthiazuron
653 2 0 |2 Author
|a Anilazine
653 2 0 |2 Author
|a Persistence
653 2 0 |2 Author
|a Bound residues
700 1 _ |a Linden, A.
|b 1
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700 1 _ |a Köppchen, S.
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700 1 _ |a Thiele, B.
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700 1 _ |a Hofmann, D.
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700 1 _ |a Mittelstaedt, W.
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700 1 _ |a Pütz, T.
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700 1 _ |a Burauel, P.
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773 _ _ |a 10.1016/j.envpol.2012.04.022
|g Vol. 168, p. 29 - 36
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