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@ARTICLE{Reddy:21670,
author = {Reddy, N.K. and Zhang, Z. and Lettinga, M.P. and Dhont,
J.K.G. and Vermant, J.},
title = {{P}robing structure in colloidal gels of thermoreversible
rodlike virus particles: {R}heology and scattering},
journal = {Journal of rheology online},
volume = {56},
issn = {0148-6055},
address = {Melville, NY [u.a.]},
publisher = {Inst.},
reportid = {PreJuSER-21670},
pages = {1153 - 1174},
year = {2012},
note = {The authors thank Jan Mewis for stimulating discussions. We
thank the EU for funding through the project NANODIRECT
(Grant No. CP-FP 213948-2). The authors are grateful to
European Synchrotron Radiation Facility (ESRF) for providing
the beamtime (experiment SC-2201) and Theyencheri Narayanan
and Michael Sztucki of ID02 for their assistance with the
SAXS experiments.},
abstract = {Aggregated suspensions of rodlike particles are commonly
encountered in soft biological materials and their solidlike
response at extremely low volume fractions is also exploited
technologically. Understanding the link between the
physicochemical parameters such as size, aspect ratio,
volume fraction, and interparticle forces with the resulting
microstructure and the subsequent rheological response
remains challenging. In the present work, suspensions of
monodisperse rodlike virus particles, whose surface is
modified by grafting with a thermoreversible polymer
poly(N-isopropylacrylamide), are used as a model system. The
repulsive and attractive contributions to the total
interaction potential can be changed independently by
varying the ionic strength and the temperature. The effects
of these changes on the strength and structure of gels have
been studied near the gel transition using a combination of
rheological and scattering measurements. Rheological
measurements of the near critical gel properties as a
function of concentration and ionic strength proved to be
more sensitive compared to scattering in resolving the
structural differences. A percolating structure can be
formed at very low volume fractions, which show a weak
dependence on the ionic strength with the anisotropy of the
repulsive interactions playing the main role in creating
more "open" structures. The intrinsic stiffness of the
rodlike particles does not affect the moduli of the gel
states very strongly. (C) 2012 The Society of Rheology.
[http://dx.doi.org/10.1122/1.4728335]},
keywords = {J (WoSType)},
cin = {ICS-3},
ddc = {530},
cid = {I:(DE-Juel1)ICS-3-20110106},
pnm = {BioSoft: Makromolekulare Systeme und biologische
Informationsverarbeitung / NANODIRECT - Toolbox for Directed
and Controlled Self-Assembly of nano-Colloids (213948)},
pid = {G:(DE-Juel1)FUEK505 / G:(EU-Grant)213948},
shelfmark = {Mechanics},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000306761300008},
doi = {10.1122/1.4728335},
url = {https://juser.fz-juelich.de/record/21670},
}