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@ARTICLE{Betzinger:21676,
author = {Betzinger, M. and Friedrich, C. and Görling, A. and
Blügel, S.},
title = {{P}recise response functions in all-electron methods:
{A}pplication to the optimized-effective-potential approach},
journal = {Physical review / B},
volume = {85},
number = {24},
issn = {1098-0121},
address = {College Park, Md.},
publisher = {APS},
reportid = {PreJuSER-21676},
pages = {245124},
year = {2012},
note = {A.G. gratefully acknowledges funding by the German Research
Council (DFG) through the Cluster of Excellence "Engineering
of Advanced Material" (www.eam.uni-erlangen.de) at the
University of Erlangen-Nuremberg.},
abstract = {The optimized-effective-potential method is a special
technique to construct local Kohn-Sham potentials from
general orbital-dependent energy functionals. In a recent
publication [M. Betzinger, C. Friedrich, S. Blugel, A.
Gorling, Phys. Rev. B 83, 045105 (2011)] we showed that
uneconomically large basis sets were required to obtain a
smooth local potential without spurious oscillations within
the full-potential linearized augmented-plane-wave method.
This could be attributed to the slow convergence behavior of
the density response function. In this paper, we derive an
incomplete-basis-set correction for the response, which
consists of two terms: (1) a correction that is formally
similar to the Pulay correction in atomic-force calculations
and (2) a numerically more important basis response term
originating from the potential dependence of the basis
functions. The basis response term is constructed from the
solutions of radial Sternheimer equations in the muffin-tin
spheres. With these corrections the local potential
converges at much smaller basis sets, at much fewer states,
and its construction becomes numerically very stable. We
analyze the improvements for rock-salt ScN and report
results for BN, AlN, and GaN, as well as the perovskites
CaTiO3, SrTiO3, and BaTiO3. The incomplete-basis-set
correction can be applied to other electronic-structure
methods with potential-dependent basis sets and opens the
perspective to investigate a broad spectrum of problems in
theoretical solid-state physics that involve response
functions.},
keywords = {J (WoSType)},
cin = {IAS-1 / PGI-1},
ddc = {530},
cid = {I:(DE-Juel1)IAS-1-20090406 / I:(DE-Juel1)PGI-1-20110106},
pnm = {Grundlagen für zukünftige Informationstechnologien},
pid = {G:(DE-Juel1)FUEK412},
shelfmark = {Physics, Condensed Matter},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000305538300005},
doi = {10.1103/PhysRevB.85.245124},
url = {https://juser.fz-juelich.de/record/21676},
}