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@ARTICLE{Nikishkin:21844,
      author       = {Nikishkin, N.I. and Huskens, J. and Assenmacher, J. and
                      Wilden, A. and Modolo, G. and Verboom, W.},
      title        = {{P}alladium-{C}atalyzed {C}ross-{C}oupling of {V}arious
                      {P}hosphorous {P}ronucleophiles with {C}hloropyrazines -
                      {S}ynthesis of {N}ovel {A}n({III})-selective {E}xtractants},
      journal      = {Organic $\&$ biomolecular chemistry},
      volume       = {10},
      issn         = {1477-0520},
      address      = {Cambridge},
      publisher    = {Royal Society of Chemistry},
      reportid     = {PreJuSER-21844},
      pages        = {5443 - 5451},
      year         = {2012},
      note         = {The authors gratefully acknowledge the financial support
                      from the EU ACSEPT (Actinide reCycling by SEParation and
                      Transmutation) project (FP7 collaborative project 211267).},
      abstract     = {Palladium-catalyzed cross-coupling of (di)chloropyrazines
                      with phosphorus pronucleophiles in the presence of a base
                      gave the phosphorylated pyrazines in $81-95\%$ yields. Based
                      on this methodology a series of appropriately functionalized
                      pyrazines was prepared as potential extractants of trivalent
                      cations from highly acidic nuclear waste. A few hydrophilic
                      derivatives exhibited a very good selectivity for Am(3+)
                      over Eu(3+) with separation factors up to 40 at pH 1 at 0.01
                      mol L(-1) ligand concentration.},
      keywords     = {J (WoSType)},
      cin          = {IEK-6},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-6-20101013},
      pnm          = {Nukleare Sicherheitsforschung / ACSEPT - Actinide reCycling
                      by SEParation and Transmutation (211267)},
      pid          = {G:(DE-Juel1)FUEK404 / G:(EU-Grant)211267},
      shelfmark    = {Chemistry, Organic},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:22707012},
      UT           = {WOS:000305764600017},
      doi          = {10.1039/c2ob25787d},
      url          = {https://juser.fz-juelich.de/record/21844},
}