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000021881 084__ $$2WoS$$aPhysics, Atomic, Molecular & Chemical
000021881 1001_ $$0P:(DE-HGF)0$$aKishikawa, Y.$$b0
000021881 245__ $$aTemperature dependence of thermal diffusion for aqueous solutions of monosaccarides, oligosaccharides, and polysaccharides
000021881 260__ $$aCambridge$$bRSC Publ.$$c2012
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000021881 440_0 $$04916$$aPhysical Chemistry Chemical Physics$$v14$$x1463-9076
000021881 500__ $$aThe authors are indebted to Jan Dhont for his kind help and to Gerhard Meier for correction reading. The technical support of Hartmut Kriegs is appreciated. The sample donation by Hayashibara co. is acknowledged. This work is partially supported by Deutsche Forschungsgemeinschaft (grant Wi 1684) and by the Ministry of Education, Science, Sports and Culture, Japan (Grant-in-Aid for Scientific Research).
000021881 520__ $$aWe studied the thermal diffusion behavior for binary aqueous solutions of glucose, maltotriose, maltohexaose, pullulan, and dextran by means of thermal diffusion forced Rayleigh scattering (TDFRS). The investigated saccharides with molar masses between 0.180 and 440 kg mol(-1) were studied in the temperature range between 15 and 55 °C. The thermal diffusion coefficient D(T) and the Soret coefficient S(T) of all solutions increase with increasing temperature. For maltohexaose and the polymers the thermal diffusion coefficient changes sign from negative to positive with increasing temperature, whereas glucose and maltotriose show only positive values in the entire investigated temperature range. While we were able to find a master curve to describe the temperature dependence of D(T), we were not able to find a similar expression for S(T). This comprehensive study allows for the first time the determination of the interaction parameters for the polymer and the solvent within the theoretical framework suggested by Würger [Phys. Rev. Lett., 2009, 102, 078302].
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000021881 7001_ $$0P:(DE-HGF)0$$aShinohara, H.$$b1
000021881 7001_ $$0P:(DE-HGF)0$$aMaeda, K.$$b2
000021881 7001_ $$0P:(DE-HGF)0$$aNakamura, Y.$$b3
000021881 7001_ $$0P:(DE-Juel1)131034$$aWiegand, S.$$b4$$uFZJ
000021881 7001_ $$0P:(DE-HGF)0$$aKita, R.$$b5
000021881 773__ $$0PERI:(DE-600)1476244-4$$a10.1039/c2cp41183k$$gVol. 14, p. 10147 - 10153$$p10147 - 10153$$q14<10147 - 10153$$tPhysical Chemistry Chemical Physics$$v14$$x1463-9076$$y2012
000021881 8567_ $$uhttp://dx.doi.org/10.1039/C2CP41183K
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