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000021909 084__ $$2WoS$$aChemistry, Physical
000021909 084__ $$2WoS$$aMaterials Science, Multidisciplinary
000021909 084__ $$2WoS$$aPhysics, Applied
000021909 084__ $$2WoS$$aPhysics, Condensed Matter
000021909 1001_ $$0P:(DE-Juel1)VDB85752$$aValov, I.$$b0$$uFZJ
000021909 245__ $$aAtomically controlled electrochemical nucleation at superionic solid electrolyte surfaces
000021909 260__ $$aBasingstoke$$bNature Publishing Group$$c2012
000021909 300__ $$a530–535
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000021909 440_0 $$011903$$aNature Materials$$v11$$x1476-1122$$y530 - 535
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000021909 500__ $$aThe authors would like to thank the German Research Foundation (DFG) and the Japan Science and Technology Agency (JST) for the financial support of the projects WA908/22-1 in Germany and that in Japan. I. S. was supported by the 'Studienstiftung des deutschen Volkes'. The assistance of T. Possinger with the graphical layout is gratefully acknowledged.
000021909 520__ $$aElectrochemical equilibrium and the transfer of mass and charge through interfaces at the atomic scale are of fundamental importance for the microscopic understanding of elementary physicochemical processes. Approaching atomic dimensions, phase instabilities and instrumentation limits restrict the resolution. Here we show an ultimate lateral, mass and charge resolution during electrochemical Ag phase formation at the surface of RbAg(4)I(5) superionic conductor thin films. We found that a small amount of electron donors in the solid electrolyte enables scanning tunnelling microscope measurements and atomically resolved imaging. We demonstrate that Ag critical nucleus formation is rate limiting. The Gibbs energy of this process takes discrete values and the number of atoms of the critical nucleus remains constant over a large range of applied potentials. Our approach is crucial to elucidate the mechanism of atomic switches and highlights the possibility of extending this method to a variety of other electrochemical systems.
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000021909 7001_ $$0P:(DE-HGF)0$$aSapezanskaia, I.$$b1
000021909 7001_ $$0P:(DE-HGF)0$$aNayak, A.$$b2
000021909 7001_ $$0P:(DE-HGF)0$$aTsuruoka, T.$$b3
000021909 7001_ $$0P:(DE-HGF)0$$aBredow, T.$$b4
000021909 7001_ $$0P:(DE-HGF)0$$aHasegawa, T.$$b5
000021909 7001_ $$0P:(DE-Juel1)VDB13645$$aStaikov, G.$$b6$$uFZJ
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000021909 7001_ $$0P:(DE-Juel1)131022$$aWaser, R.$$b8$$uFZJ
000021909 773__ $$0PERI:(DE-600)2088679-2$$a10.1038/nmat3307$$gVol. 11$$p530–535$$q11$$tNature materials$$v11$$x1476-1122$$y2012
000021909 8567_ $$uhttp://dx.doi.org/10.1038/nmat3307
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