TY - JOUR AU - Wagner, C. AU - Fournier, N. AU - Tautz, F.S. AU - Temirov, R. TI - Measurement of the Binding Energies of the Organic-Metal Perylene-Teracarboxylic-Dianhydride/Au(111) Bonds by Molecular Manipulation Using an Atomic Force Microscope JO - Physical review letters VL - 109 SN - 0031-9007 CY - College Park, Md. PB - APS M1 - PreJuSER-22290 SP - 076102 PY - 2012 N1 - We gratefully acknowledge T. Lippert, N. Attig, O. Buchner, and W. Homberg (Forschungszentrum Julich) who have supported us with CPU time on JUDGE. We thank D. Park and J. Mayer from RWTH Aachen for help with the focused ion beam. R. T. thanks the Helmholtz-Gemeinschaft for financial support for his Young Investigator Research Group. This work has been supported by the Deutsche Forschungsgemeinschaft under projects TA244/5-1 and TA244/5-2. AB - Based on single molecule manipulation experiments in a combined scanning tunneling microscope/frequency modulated atomic force microscope, we quantify the individual binding energy contributions to an organic-metal bond experimentally. The method allows the determination of contributions from, e. g., local chemical bonds, metal-molecule hybridization, and van der Waals interactions, as well as the total adsorption energy. KW - J (WoSType) LB - PUB:(DE-HGF)16 UR - <Go to ISI:>//WOS:000307709400030 DO - DOI:10.1103/PhysRevLett.109.076102 UR - https://juser.fz-juelich.de/record/22290 ER -