000022291 001__ 22291
000022291 005__ 20190625111439.0
000022291 0247_ $$2pmid$$apmid:22524248
000022291 0247_ $$2DOI$$a10.1021/ic202644t
000022291 0247_ $$2WOS$$aWOS:000303952900032
000022291 0247_ $$2altmetric$$aaltmetric:710416
000022291 037__ $$aPreJuSER-22291
000022291 041__ $$aeng
000022291 082__ $$a540
000022291 084__ $$2WoS$$aChemistry, Inorganic & Nuclear
000022291 1001_ $$0P:(DE-HGF)0$$aDulcevscaia, G.M.$$b0
000022291 245__ $$aCluster-based Networks: 1D and 2D Coordination Polymers Based on {MnFe2(µ3-O)}-type Clusters
000022291 260__ $$aWeinheim$$bWiley-VCH$$c2012
000022291 300__ $$a5110 -5117
000022291 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article
000022291 3367_ $$2DataCite$$aOutput Types/Journal article
000022291 3367_ $$00$$2EndNote$$aJournal Article
000022291 3367_ $$2BibTeX$$aARTICLE
000022291 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000022291 3367_ $$2DRIVER$$aarticle
000022291 440_0 $$011961$$aEuropean Journal of Inorganic Chemistry$$v51$$x1434-1948$$y9
000022291 500__ $$3POF3_Assignment on 2016-02-29
000022291 500__ $$aFinancial support from the Swiss National Science Foundation (SCOPES IZ73Z0_127925), the German Federal Ministry of Education and Research (project MDA 08/022), the Academy of Sciences of Moldova (project No. 09.820.05.10GF), the Supreme Council for Science and Technological Development of the Republic of Moldova (projects 09.836.05.02A and 11.817.05.03A), and the EU (POLYMAG, IIF contract no. 252984) are acknowledged. We thank Prof. H. Stoeckli-Evans for the collection of crystallographic data sets for compound 1.
000022291 520__ $$aA straightforward approach to heterometallic Mn-Fe cluster-based coordination polymers is presented. By employing a mixed-valent μ(3)-oxo trinuclear manganese(II/III) pivalate cluster, isolated as [Mn(II)Mn(III)(2)O(O(2)CCMe(3))(6)(hmta)(3)]·(solvent) (hmta = hexamethylenetetramine; solvent = n-propanol (1), toluene (2)) in the reaction with a μ(3)-oxo trinuclear iron(III) pivalate cluster compound, [Fe(3)O(O(2)CCMe(3))(6)(H(2)O)(3)]O(2)CCMe(3)·2Me(3)CCO(2)H, three new heterometallic {Mn(II)Fe(III)(2)} cluster-based coordination polymers were obtained: the one-dimensional polymer chain compounds {[MnFe(2)O(O(2)CCMe(3))(6)(hmta)(2)]·0.5MeCN}(n) (3) and {[MnFe(2)O(O(2)CCMe(3))(6)(hmta)(2)]·Me(3)CCO(2)H·(n-hexane)}(n) (4) and the two-dimensional layer compound {[MnFe(2)O(O(2)CCMe(3))(6)(hmta)(1.5)]·(toluene)}(n) (5). Single-crystal X-ray diffraction analysis reveals a μ(3)-oxo trinuclear pivalate cluster building block as the main constituent in all polymer compounds. Different M:hmta ratios in 1-5 are related to the different structural functions of the N-containing ligand. In clusters 1 and 2, three hmta ligands are monodentate, whereas in chains 3 and 4 two hmta ligands act as bridging ligands and one is a monodentate ligand; in 5, all hmta molecules act as bidentate bridges. Magnetic studies indicate dominant antiferromagnetic interactions between the metal centers in both homometallic {Mn(3)}-type clusters 1 and 2 and heterometallic {MnFe(2)}-type coordination polymers 3-5. Modeling of the magnetic susceptibility data to a isotropic model Hamiltonian yields least-squares fits for the following parameters: J(1)(Mn(II)-Mn(III)) = -6.6 cm(-1) and J(2)(Mn(III)-Mn(III)) = -5.4 cm(-1) for 1; J(1) = -5.5 cm(-1) and J(2)(Mn(III)-Mn(III)) = -3.9 cm(-1) for 2; J(1)(Mn(II)-Fe(III)) = -17.1 cm(-1) and J(2)(Fe(III)-Fe(III)) = -43.7 cm(-1) for 3; J(1) = -23.8 cm(-1) and J(2) = -53.4 cm(-1) for 4; J(1) = -13.3 cm(-1) and J(2) = -35.4 cm(-1) for 5. Intercluster coupling plays a significant role in all compounds 1-5.
000022291 536__ $$0G:(DE-Juel1)FUEK412$$2G:(DE-HGF)$$aGrundlagen für zukünftige Informationstechnologien$$cP42$$x0
000022291 536__ $$0G:(EU-Grant)252984$$aPOLYMAG - Magnetic Coordination Cluster Polymers (252984)$$c252984$$fFP7-PEOPLE-2009-IIF$$x1
000022291 588__ $$aDataset connected to Web of Science, Pubmed
000022291 650_7 $$2WoSType$$aJ
000022291 7001_ $$0P:(DE-HGF)0$$aFilippova, I.G.$$b1
000022291 7001_ $$0P:(DE-HGF)0$$aSpeldrich, M.$$b2
000022291 7001_ $$0P:(DE-HGF)0$$aLeusen, J. van$$b3
000022291 7001_ $$0P:(DE-HGF)0$$aKravtsov, V.C.$$b4
000022291 7001_ $$0P:(DE-HGF)0$$aBaca, S.G.$$b5
000022291 7001_ $$0P:(DE-Juel1)VDB12080$$aKögerler, P.$$b6$$uFZJ
000022291 7001_ $$0P:(DE-HGF)0$$aLiu, S.-X.$$b7
000022291 7001_ $$0P:(DE-HGF)0$$aDecurtins, S.$$b8
000022291 773__ $$0PERI:(DE-600)1475009-0$$a10.1021/ic202644t$$gVol. 51, p. 5110 -5117$$p5110 -5117$$q51<5110 -5117$$tEuropean journal of inorganic chemistry$$v51$$x1434-1948$$y2012
000022291 8567_ $$uhttp://dx.doi.org/10.1021/ic202644t
000022291 909CO $$ooai:juser.fz-juelich.de:22291$$pec_fundedresources$$pVDB$$popenaire
000022291 915__ $$0StatID:(DE-HGF)0010$$2StatID$$aJCR/ISI refereed
000022291 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR
000022291 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index
000022291 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000022291 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000022291 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bThomson Reuters Master Journal List
000022291 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS
000022291 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000022291 915__ $$0StatID:(DE-HGF)0310$$2StatID$$aDBCoverage$$bNCBI Molecular Biology Database
000022291 915__ $$0StatID:(DE-HGF)1020$$2StatID$$aDBCoverage$$bCurrent Contents - Social and Behavioral Sciences
000022291 9141_ $$y2012
000022291 9131_ $$0G:(DE-Juel1)FUEK412$$1G:(DE-HGF)POF2-420$$2G:(DE-HGF)POF2-400$$aDE-HGF$$bSchlüsseltechnologien$$kP42$$lGrundlagen für zukünftige Informationstechnologien (FIT)$$vGrundlagen für zukünftige Informationstechnologien$$x0
000022291 9132_ $$0G:(DE-HGF)POF3-529H$$1G:(DE-HGF)POF3-520$$2G:(DE-HGF)POF3-500$$aDE-HGF$$bKey Technologies$$lFuture Information Technology - Fundamentals, Novel Concepts and Energy Efficiency (FIT)$$vAddenda$$x0
000022291 9201_ $$0I:(DE-Juel1)PGI-6-20110106$$gPGI$$kPGI-6$$lElektronische Eigenschaften$$x0
000022291 970__ $$aVDB:(DE-Juel1)138754
000022291 980__ $$aVDB
000022291 980__ $$aConvertedRecord
000022291 980__ $$ajournal
000022291 980__ $$aI:(DE-Juel1)PGI-6-20110106
000022291 980__ $$aUNRESTRICTED