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000022292 084__ $$2WoS$$aChemistry, Inorganic & Nuclear
000022292 1001_ $$0P:(DE-HGF)0$$aAntonova, E.$$b0
000022292 245__ $$aA C2-symmetric Antimonato Polyoxovanadate Cluster [V16Sb4O42(H2O)]8– derived from the {V18O42} archetype
000022292 260__ $$aLondon$$bSoc.$$c2012
000022292 300__ $$a6957 - 6962
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000022292 440_0 $$015301$$aDalton Transactions$$v42$$x1477-9226
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000022292 520__ $$aThe new antimonato polyoxovanadate [V(IV)(16)Sb(III)(4)O(42)(H(2)O)](8-) cluster (1a) is the main structural motif of the solvothermally obtained compound {(trenH(2))Zn(tren)}(2)[V(16)Sb(4)O(42)(H(2)O)]·xH(2)O (x = 6-10) (1) (tren = tris(2-aminoethyl)amine). The C(2)-symmetric cluster structure is closely related to the {V(18)O(42)} archetype. 1 crystallizes in the monoclinic space group C2/c with a = 30.7070(19) Å, b = 13.9512(5) Å, c = 23.1435(14) Å, β = 128.076(6)°, and V = 7804.8(7) Å(3). The orientation of the [Sb(III)(2)O(5)](4-) groups in each cluster leads to intermolecular Sb···O contacts and the formation of channels between the clusters. [Zn(tren)(trenH(2))] complexes with trigonal bipyramidal coordination environments are located between the [V(16)Sb(4)O(42)(H(2)O)](8-) anions, and form a three dimensional network with them via strong N-H···O hydrogen bonds. Up to 250 °C crystal water molecules are emitted, which are reversibly incorporated in humid air.
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000022292 650_2 $$2MeSH$$aAntimony: chemistry
000022292 650_2 $$2MeSH$$aModels, Molecular
000022292 650_2 $$2MeSH$$aMolecular Conformation
000022292 650_2 $$2MeSH$$aOrganometallic Compounds: chemistry
000022292 650_2 $$2MeSH$$aVanadates: chemical synthesis
000022292 650_2 $$2MeSH$$aVanadates: chemistry
000022292 650_2 $$2MeSH$$aWater: chemistry
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000022292 650_7 $$07440-36-0$$2NLM Chemicals$$aAntimony
000022292 650_7 $$07732-18-5$$2NLM Chemicals$$aWater
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000022292 7001_ $$0P:(DE-HGF)0$$aNäther, C.$$b1
000022292 7001_ $$0P:(DE-Juel1)VDB12080$$aKögerler, P.$$b2$$uFZJ
000022292 7001_ $$0P:(DE-HGF)0$$aBensch, W.$$b3
000022292 773__ $$0PERI:(DE-600)1472887-4$$a10.1039/c2dt30319a$$gVol. 41, p. 6957 - 6962$$p6957 - 6962$$q41<6957 - 6962$$tDalton transactions$$v41$$x1477-9226$$y2012
000022292 8567_ $$uhttp://dx.doi.org/10.1039/C2DT30319A
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