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@ARTICLE{Antonova:22292,
      author       = {Antonova, E. and Näther, C. and Kögerler, P. and Bensch,
                      W.},
      title        = {{A} {C}2-symmetric {A}ntimonato {P}olyoxovanadate {C}luster
                      [{V}16{S}b4{O}42({H}2{O})]8– derived from the {{V}18{O}42}
                      archetype},
      journal      = {Dalton transactions},
      volume       = {41},
      issn         = {1477-9226},
      address      = {London},
      publisher    = {Soc.},
      reportid     = {PreJuSER-22292},
      pages        = {6957 - 6962},
      year         = {2012},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {The new antimonato polyoxovanadate
                      [V(IV)(16)Sb(III)(4)O(42)(H(2)O)](8-) cluster (1a) is the
                      main structural motif of the solvothermally obtained
                      compound
                      {(trenH(2))Zn(tren)}(2)[V(16)Sb(4)O(42)(H(2)O)]·xH(2)O (x =
                      6-10) (1) (tren = tris(2-aminoethyl)amine). The
                      C(2)-symmetric cluster structure is closely related to the
                      {V(18)O(42)} archetype. 1 crystallizes in the monoclinic
                      space group C2/c with a = 30.7070(19) Å, b = 13.9512(5) Å,
                      c = 23.1435(14) Å, β = 128.076(6)°, and V = 7804.8(7)
                      Å(3). The orientation of the [Sb(III)(2)O(5)](4-) groups in
                      each cluster leads to intermolecular Sb···O contacts and
                      the formation of channels between the clusters.
                      [Zn(tren)(trenH(2))] complexes with trigonal bipyramidal
                      coordination environments are located between the
                      [V(16)Sb(4)O(42)(H(2)O)](8-) anions, and form a three
                      dimensional network with them via strong N-H···O hydrogen
                      bonds. Up to 250 °C crystal water molecules are emitted,
                      which are reversibly incorporated in humid air.},
      keywords     = {Antimony: chemistry / Models, Molecular / Molecular
                      Conformation / Organometallic Compounds: chemistry /
                      Vanadates: chemical synthesis / Vanadates: chemistry /
                      Water: chemistry / Organometallic Compounds (NLM Chemicals)
                      / Vanadates (NLM Chemicals) / Antimony (NLM Chemicals) /
                      Water (NLM Chemicals) / J (WoSType)},
      cin          = {PGI-6},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-6-20110106},
      pnm          = {Grundlagen für zukünftige Informationstechnologien},
      pid          = {G:(DE-Juel1)FUEK412},
      shelfmark    = {Chemistry, Inorganic $\&$ Nuclear},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:22495299},
      UT           = {WOS:000304487400010},
      doi          = {10.1039/c2dt30319a},
      url          = {https://juser.fz-juelich.de/record/22292},
}