Home > Publications database > A C2-symmetric Antimonato Polyoxovanadate Cluster [V16Sb4O42(H2O)]8– derived from the {V18O42} archetype > print

001     22292
005     20190625110352.0
024 7 _ |a pmid:22495299
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024 7 _ |a 10.1039/C2DT30319A
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024 7 _ |a WOS:000304487400010
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024 7 _ |a 2128/7522
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024 7 _ |a altmetric:660984
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037 _ _ |a PreJuSER-22292
041 _ _ |a eng
082 _ _ |a 540
084 _ _ |2 WoS
|a Chemistry, Inorganic & Nuclear
100 1 _ |a Antonova, E.
|b 0
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245 _ _ |a A C2-symmetric Antimonato Polyoxovanadate Cluster [V16Sb4O42(H2O)]8– derived from the {V18O42} archetype
260 _ _ |a London
|b Soc.
|c 2012
300 _ _ |a 6957 - 6962
336 7 _ |a Journal Article
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336 7 _ |a article
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440 _ 0 |a Dalton Transactions
|x 1477-9226
|0 15301
|v 42
500 _ _ |3 POF3_Assignment on 2016-02-29
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a The new antimonato polyoxovanadate [V(IV)(16)Sb(III)(4)O(42)(H(2)O)](8-) cluster (1a) is the main structural motif of the solvothermally obtained compound {(trenH(2))Zn(tren)}(2)[V(16)Sb(4)O(42)(H(2)O)]·xH(2)O (x = 6-10) (1) (tren = tris(2-aminoethyl)amine). The C(2)-symmetric cluster structure is closely related to the {V(18)O(42)} archetype. 1 crystallizes in the monoclinic space group C2/c with a = 30.7070(19) Å, b = 13.9512(5) Å, c = 23.1435(14) Å, β = 128.076(6)°, and V = 7804.8(7) Å(3). The orientation of the [Sb(III)(2)O(5)](4-) groups in each cluster leads to intermolecular Sb···O contacts and the formation of channels between the clusters. [Zn(tren)(trenH(2))] complexes with trigonal bipyramidal coordination environments are located between the [V(16)Sb(4)O(42)(H(2)O)](8-) anions, and form a three dimensional network with them via strong N-H···O hydrogen bonds. Up to 250 °C crystal water molecules are emitted, which are reversibly incorporated in humid air.
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650 _ 2 |2 MeSH
|a Antimony: chemistry
650 _ 2 |2 MeSH
|a Models, Molecular
650 _ 2 |2 MeSH
|a Molecular Conformation
650 _ 2 |2 MeSH
|a Organometallic Compounds: chemistry
650 _ 2 |2 MeSH
|a Vanadates: chemical synthesis
650 _ 2 |2 MeSH
|a Vanadates: chemistry
650 _ 2 |2 MeSH
|a Water: chemistry
650 _ 7 |0 0
|2 NLM Chemicals
|a Organometallic Compounds
650 _ 7 |0 0
|2 NLM Chemicals
|a Vanadates
650 _ 7 |0 7440-36-0
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|a Antimony
650 _ 7 |0 7732-18-5
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|a Water
650 _ 7 |a J
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700 1 _ |a Näther, C.
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700 1 _ |a Kögerler, P.
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700 1 _ |a Bensch, W.
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773 _ _ |a 10.1039/c2dt30319a
|g Vol. 41, p. 6957 - 6962
|p 6957 - 6962
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|t Dalton transactions
|v 41
|y 2012
|x 1477-9226
856 7 _ |u http://dx.doi.org/10.1039/C2DT30319A
856 4 _ |u https://juser.fz-juelich.de/record/22292/files/FZJ-22292.pdf
|y Published under German "Allianz" Licensing conditions on 2012-03-21. Available in OpenAccess from 2013-03-21
|z Published final document.
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914 1 _ |y 2012
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