TY  - JOUR
AU  - Fielden, J.
AU  - Speldrich, M.
AU  - Besson, C.
AU  - Kögerler, P.
TI  - Chiral Hexanuclear Ferric Wheels
JO  - Inorganic chemistry
VL  - 51
SN  - 0020-1669
CY  - Washington, DC
PB  - American Chemical Society
M1  - PreJuSER-22300
SP  - 2734 - 2736
PY  - 2012
N1  - We thank Joost de Groot (Forschungszentrum Julich) and Louise Natrajan (University of Manchester) for help with X-ray diffraction and paramagnetic NMR. Work at the Ames Laboratory was supported by the Department of Energy, Basic Energy Sciences, under Contract DE-AC02-07CH11358.
AB  - The homochiral iron(III) wheels [Fe(6){(S)-pedea}(6)Cl(6)] and [Fe(6){(R)-pedea)}(6)Cl(6)] [(R)- and (S)-2; pedea = phenylethylaminodiethoxide] exhibit high optical activities and antiferromagnetic exchange. These homochiral products react with each other, producing the centrosymmetric, crystallographically characterized [Fe(6){(S)-pedea}(3){(R)-pedea}(3)Cl(6)] diastereomer [(RSRSRS)-2]. (1)H NMR and UV-vis studies indicate that exchange processes are slow in both homo- and heterochiral systems but that, upon combination, the reaction between (R)- and (S)-2 occurs quickly.
KW  - Circular Dichroism
KW  - Crystallography, X-Ray
KW  - Ferric Compounds: chemistry
KW  - Magnetic Resonance Spectroscopy
KW  - Models, Molecular
KW  - Stereoisomerism
KW  - Ferric Compounds (NLM Chemicals)
KW  - J (WoSType)
LB  - PUB:(DE-HGF)16
C6  - pmid:22332882
UR  - <Go to ISI:>//WOS:000301007100006
DO  - DOI:10.1021/ic300042q
UR  - https://juser.fz-juelich.de/record/22300
ER  -