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@ARTICLE{Fielden:22300,
      author       = {Fielden, J. and Speldrich, M. and Besson, C. and Kögerler,
                      P.},
      title        = {{C}hiral {H}exanuclear {F}erric {W}heels},
      journal      = {Inorganic chemistry},
      volume       = {51},
      issn         = {0020-1669},
      address      = {Washington, DC},
      publisher    = {American Chemical Society},
      reportid     = {PreJuSER-22300},
      pages        = {2734 - 2736},
      year         = {2012},
      note         = {We thank Joost de Groot (Forschungszentrum Julich) and
                      Louise Natrajan (University of Manchester) for help with
                      X-ray diffraction and paramagnetic NMR. Work at the Ames
                      Laboratory was supported by the Department of Energy, Basic
                      Energy Sciences, under Contract DE-AC02-07CH11358.},
      abstract     = {The homochiral iron(III) wheels [Fe(6){(S)-pedea}(6)Cl(6)]
                      and [Fe(6){(R)-pedea)}(6)Cl(6)] [(R)- and (S)-2; pedea =
                      phenylethylaminodiethoxide] exhibit high optical activities
                      and antiferromagnetic exchange. These homochiral products
                      react with each other, producing the centrosymmetric,
                      crystallographically characterized
                      [Fe(6){(S)-pedea}(3){(R)-pedea}(3)Cl(6)] diastereomer
                      [(RSRSRS)-2]. (1)H NMR and UV-vis studies indicate that
                      exchange processes are slow in both homo- and heterochiral
                      systems but that, upon combination, the reaction between
                      (R)- and (S)-2 occurs quickly.},
      keywords     = {Circular Dichroism / Crystallography, X-Ray / Ferric
                      Compounds: chemistry / Magnetic Resonance Spectroscopy /
                      Models, Molecular / Stereoisomerism / Ferric Compounds (NLM
                      Chemicals) / J (WoSType)},
      cin          = {PGI-6},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-6-20110106},
      pnm          = {Grundlagen für zukünftige Informationstechnologien},
      pid          = {G:(DE-Juel1)FUEK412},
      shelfmark    = {Chemistry, Inorganic $\&$ Nuclear},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:22332882},
      UT           = {WOS:000301007100006},
      doi          = {10.1021/ic300042q},
      url          = {https://juser.fz-juelich.de/record/22300},
}