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| 001 | 22300 | ||
| 005 | 20190625111407.0 | ||
| 024 | 7 | _ | |2 pmid |a pmid:22332882 |
| 024 | 7 | _ | |2 DOI |a 10.1021/ic300042q |
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| 024 | 7 | _ | |a altmetric:604745 |2 altmetric |
| 037 | _ | _ | |a PreJuSER-22300 |
| 041 | _ | _ | |a eng |
| 082 | _ | _ | |a 540 |
| 084 | _ | _ | |2 WoS |a Chemistry, Inorganic & Nuclear |
| 100 | 1 | _ | |0 P:(DE-HGF)0 |a Fielden, J. |b 0 |
| 245 | _ | _ | |a Chiral Hexanuclear Ferric Wheels |
| 260 | _ | _ | |a Washington, DC |b American Chemical Society |c 2012 |
| 300 | _ | _ | |a 2734 - 2736 |
| 336 | 7 | _ | |a Journal Article |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |
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| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a article |2 DRIVER |
| 440 | _ | 0 | |0 14061 |a Inorganic Chemistry |v 51 |x 0020-1669 |y 5 |
| 500 | _ | _ | |3 POF3_Assignment on 2016-02-29 |
| 500 | _ | _ | |a We thank Joost de Groot (Forschungszentrum Julich) and Louise Natrajan (University of Manchester) for help with X-ray diffraction and paramagnetic NMR. Work at the Ames Laboratory was supported by the Department of Energy, Basic Energy Sciences, under Contract DE-AC02-07CH11358. |
| 520 | _ | _ | |a The homochiral iron(III) wheels [Fe(6){(S)-pedea}(6)Cl(6)] and [Fe(6){(R)-pedea)}(6)Cl(6)] [(R)- and (S)-2; pedea = phenylethylaminodiethoxide] exhibit high optical activities and antiferromagnetic exchange. These homochiral products react with each other, producing the centrosymmetric, crystallographically characterized [Fe(6){(S)-pedea}(3){(R)-pedea}(3)Cl(6)] diastereomer [(RSRSRS)-2]. (1)H NMR and UV-vis studies indicate that exchange processes are slow in both homo- and heterochiral systems but that, upon combination, the reaction between (R)- and (S)-2 occurs quickly. |
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| 588 | _ | _ | |a Dataset connected to Web of Science, Pubmed |
| 650 | _ | 2 | |2 MeSH |a Circular Dichroism |
| 650 | _ | 2 | |2 MeSH |a Crystallography, X-Ray |
| 650 | _ | 2 | |2 MeSH |a Ferric Compounds: chemistry |
| 650 | _ | 2 | |2 MeSH |a Magnetic Resonance Spectroscopy |
| 650 | _ | 2 | |2 MeSH |a Models, Molecular |
| 650 | _ | 2 | |2 MeSH |a Stereoisomerism |
| 650 | _ | 7 | |0 0 |2 NLM Chemicals |a Ferric Compounds |
| 650 | _ | 7 | |2 WoSType |a J |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Speldrich, M. |b 1 |
| 700 | 1 | _ | |0 P:(DE-Juel1)140288 |a Besson, C. |b 2 |u FZJ |
| 700 | 1 | _ | |0 P:(DE-Juel1)VDB12080 |a Kögerler, P. |b 3 |u FZJ |
| 773 | _ | _ | |0 PERI:(DE-600)1484438-2 |a 10.1021/ic300042q |g Vol. 51, p. 2734 - 2736 |p 2734 - 2736 |q 51<2734 - 2736 |t Inorganic chemistry |v 51 |x 0020-1669 |y 2012 |
| 856 | 7 | _ | |u http://dx.doi.org/10.1021/ic300042q |
| 909 | C | O | |o oai:juser.fz-juelich.de:22300 |p VDB |
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| 914 | 1 | _ | |y 2012 |
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