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000022301 084__ $$2WoS$$aChemistry, Inorganic & Nuclear
000022301 1001_ $$0P:(DE-HGF)0$$aFielden, J.$$b0
000022301 245__ $$a[CoxCu1x(DDOP)(OH2)(NO3)](NO3): hydrogen bond-driven distortion of cobalt(II) by solid solution ‘network mismatch’
000022301 260__ $$aLondon$$bSoc.$$c2012
000022301 300__ $$a4927 - 4934
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000022301 440_0 $$015301$$aDalton Transactions$$v411$$x1477-9226
000022301 500__ $$3POF3_Assignment on 2016-02-29
000022301 500__ $$aWe thank Claire Besson for suggesting use of the bond-valence method, Georg Seeber for X-ray diffraction data for compound 2, Kevin Lamberts for X-ray diffraction data on the additional solid solutions (ESI) and Geoff Cooper for re-synthesis of 4. JF and DL both acknowledge the EPSRC for funding.
000022301 520__ $$aLate-first row transition metal nitrate complexes of the tetradentate N-donor ligand cis-3,5-bis[(2-pyridinyleneamino]-trans-hydroxycyclohexane (DDOP) adopt a mono-cationic [M(DDOP)(H(2)O)(NO(3))](+) structure (M = Co, 1; Cu, 2; Zn, 3) in which the DDOP ligand occupies the equatorial plane. The complexes are essentially isostructural and isomorphous, allowing the Co(II) and Cu(II) complexes to co-crystallize in mixed-metal solid solutions with the formula [Co(x)Cu(1-x)(DDOP)(NO(3))(H(2)O)](NO(3)), where x = 0.4 (4), 0.1 (5), and 0.7 (6). For 4, structural and magnetochemical analysis indicate that the geometry of the octahedral Co(II) complex distorts to match that of the dominant Jahn-Teller distorted Cu(II) center. Magnetic susceptibility data of octahedral Co(II) are sensitive to ligand geometry distortions and have been analyzed accordingly, comparing 4 to the reference systems 1 and 2. Bond valence calculations have been used to estimate the relative stabilities of the six hydrogen bonded networks, suggesting that the stretching of the Co(II) coordination sphere 4 in is assisted by adoption of the most stable hydrogen bonded network; but that in 6 this is overcome by a higher loading of Co. This family of complexes therefore represent predictable metal-based tectons which can help probe the influence of secondary non-covalent interactions over metal coordination geometries and properties.
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000022301 7001_ $$0P:(DE-HGF)0$$aLong, D.-L.$$b1
000022301 7001_ $$0P:(DE-HGF)0$$aSpeldrich, M.$$b2
000022301 7001_ $$0P:(DE-Juel1)VDB12080$$aKögerler, P.$$b3$$uFZJ
000022301 7001_ $$0P:(DE-HGF)0$$aCronin, L.$$b4
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000022301 8567_ $$uhttp://dx.doi.org/10.1039/C2DT11055E
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