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@ARTICLE{Malaestean:22302,
      author       = {Malaestean, I.L. and Kutluca Alici, M. and Ellern, A. and
                      van Leusen, J. and Schilder, H. and Speldrich, M. and Baca,
                      S.G. and Kögerler, P.},
      title        = {{L}inear, {Z}ig-zag and {H}elical {C}erium({III})
                      {C}oordination {P}olymers},
      journal      = {Crystal growth $\&$ design},
      volume       = {12},
      issn         = {1528-7483},
      address      = {Washington, DC},
      publisher    = {ACS Publ.},
      reportid     = {PreJuSER-22302},
      pages        = {1593 - 1602},
      year         = {2012},
      note         = {We thank Yutian Wang for collecting crystallographic data
                      sets for compounds 1, 3, and S. Work at the Ames Laboratory
                      was supported by the Department of Energy-Basic Energy
                      Sciences under Contract No. DE-AC02-07CH11358.},
      abstract     = {Five novel one-dimensional cerium(III) carboxylate
                      coordination polymers, [Ce(O2CCH2CHMe2)(3)(EtOH)(2)](n) (1),
                      {[Ce(O2CCH2Me)(3)(H2O)]center dot 0.5(4,4'-bpy)}(n) (2;
                      4,4'-bpy = 4,4'-bipyridine),
                      {[Ce-2(O2CCHMe2)(6)(H2O)(3)]}(n) (3),
                      {[Ce-3(O2CCHMe2)(9)(nPrOH)(4)]}(n) (4), and
                      {[Ce-3(O2CCHMe2)(9)(HO2CCHMe2)(2-)(H2O)(2)]center dot
                      2Me(2)CHCO(2)H}(n) (5), showcase the surprisingly consistent
                      tendency of Ce(III) coordination network structures to adopt
                      one-dimensional connection modes. The type of carboxylate as
                      well as the reaction solvents determines the exact bridging
                      versus end-on coordination modes for the carboxylates and,
                      in turn, discriminate between linear, zigzag, and helical
                      arrangements. Detailed magnetochemical analyses reveal
                      pronounced single-ion effects and the expected weak
                      antiferromagnetic coupling.},
      keywords     = {J (WoSType)},
      cin          = {PGI-6},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-6-20110106},
      pnm          = {Grundlagen für zukünftige Informationstechnologien},
      pid          = {G:(DE-Juel1)FUEK412},
      shelfmark    = {Chemistry, Multidisciplinary / Crystallography / Materials
                      Science, Multidisciplinary},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000301098700071},
      doi          = {10.1021/cg2016337},
      url          = {https://juser.fz-juelich.de/record/22302},
}