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| Hauptseite > Publikationsdatenbank > Linear, Zig-zag and Helical Cerium(III) Coordination Polymers > print |
| Hauptseite > Publikationsdatenbank > Linear, Zig-zag and Helical Cerium(III) Coordination Polymers > print |
| 001 | 22302 | ||
| 005 | 20180210142949.0 | ||
| 024 | 7 | _ | |2 DOI |a 10.1021/cg2016337 |
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| 037 | _ | _ | |a PreJuSER-22302 |
| 041 | _ | _ | |a eng |
| 082 | _ | _ | |a 540 |
| 084 | _ | _ | |2 WoS |a Chemistry, Multidisciplinary |
| 084 | _ | _ | |2 WoS |a Crystallography |
| 084 | _ | _ | |2 WoS |a Materials Science, Multidisciplinary |
| 100 | 1 | _ | |0 P:(DE-HGF)0 |a Malaestean, I.L. |b 0 |
| 245 | _ | _ | |a Linear, Zig-zag and Helical Cerium(III) Coordination Polymers |
| 260 | _ | _ | |a Washington, DC |b ACS Publ. |c 2012 |
| 300 | _ | _ | |a 1593 - 1602 |
| 336 | 7 | _ | |a Journal Article |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a article |2 DRIVER |
| 440 | _ | 0 | |0 24841 |a Crystal Growth and Design |v 12 |y 3 |
| 500 | _ | _ | |3 POF3_Assignment on 2016-02-29 |
| 500 | _ | _ | |a We thank Yutian Wang for collecting crystallographic data sets for compounds 1, 3, and S. Work at the Ames Laboratory was supported by the Department of Energy-Basic Energy Sciences under Contract No. DE-AC02-07CH11358. |
| 520 | _ | _ | |a Five novel one-dimensional cerium(III) carboxylate coordination polymers, [Ce(O2CCH2CHMe2)(3)(EtOH)(2)](n) (1), {[Ce(O2CCH2Me)(3)(H2O)]center dot 0.5(4,4'-bpy)}(n) (2; 4,4'-bpy = 4,4'-bipyridine), {[Ce-2(O2CCHMe2)(6)(H2O)(3)]}(n) (3), {[Ce-3(O2CCHMe2)(9)(nPrOH)(4)]}(n) (4), and {[Ce-3(O2CCHMe2)(9)(HO2CCHMe2)(2-)(H2O)(2)]center dot 2Me(2)CHCO(2)H}(n) (5), showcase the surprisingly consistent tendency of Ce(III) coordination network structures to adopt one-dimensional connection modes. The type of carboxylate as well as the reaction solvents determines the exact bridging versus end-on coordination modes for the carboxylates and, in turn, discriminate between linear, zigzag, and helical arrangements. Detailed magnetochemical analyses reveal pronounced single-ion effects and the expected weak antiferromagnetic coupling. |
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| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Kutluca Alici, M. |b 1 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Ellern, A. |b 2 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a van Leusen, J. |b 3 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Schilder, H. |b 4 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Speldrich, M. |b 5 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Baca, S.G. |b 6 |
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| 773 | _ | _ | |0 PERI:(DE-600)2048329-6 |a 10.1021/cg2016337 |g Vol. 12, p. 1593 - 1602 |p 1593 - 1602 |q 12<1593 - 1602 |t Crystal growth & design |v 12 |x 1528-7483 |y 2012 |
| 856 | 7 | _ | |u http://dx.doi.org/10.1021/cg2016337 |
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