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024 7 _ |2 DOI
|a 10.1021/cg2016337
024 7 _ |2 WOS
|a WOS:000301098700071
037 _ _ |a PreJuSER-22302
041 _ _ |a eng
082 _ _ |a 540
084 _ _ |2 WoS
|a Chemistry, Multidisciplinary
084 _ _ |2 WoS
|a Crystallography
084 _ _ |2 WoS
|a Materials Science, Multidisciplinary
100 1 _ |0 P:(DE-HGF)0
|a Malaestean, I.L.
|b 0
245 _ _ |a Linear, Zig-zag and Helical Cerium(III) Coordination Polymers
260 _ _ |a Washington, DC
|b ACS Publ.
|c 2012
300 _ _ |a 1593 - 1602
336 7 _ |a Journal Article
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440 _ 0 |0 24841
|a Crystal Growth and Design
|v 12
|y 3
500 _ _ |3 POF3_Assignment on 2016-02-29
500 _ _ |a We thank Yutian Wang for collecting crystallographic data sets for compounds 1, 3, and S. Work at the Ames Laboratory was supported by the Department of Energy-Basic Energy Sciences under Contract No. DE-AC02-07CH11358.
520 _ _ |a Five novel one-dimensional cerium(III) carboxylate coordination polymers, [Ce(O2CCH2CHMe2)(3)(EtOH)(2)](n) (1), {[Ce(O2CCH2Me)(3)(H2O)]center dot 0.5(4,4'-bpy)}(n) (2; 4,4'-bpy = 4,4'-bipyridine), {[Ce-2(O2CCHMe2)(6)(H2O)(3)]}(n) (3), {[Ce-3(O2CCHMe2)(9)(nPrOH)(4)]}(n) (4), and {[Ce-3(O2CCHMe2)(9)(HO2CCHMe2)(2-)(H2O)(2)]center dot 2Me(2)CHCO(2)H}(n) (5), showcase the surprisingly consistent tendency of Ce(III) coordination network structures to adopt one-dimensional connection modes. The type of carboxylate as well as the reaction solvents determines the exact bridging versus end-on coordination modes for the carboxylates and, in turn, discriminate between linear, zigzag, and helical arrangements. Detailed magnetochemical analyses reveal pronounced single-ion effects and the expected weak antiferromagnetic coupling.
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|a Speldrich, M.
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|a Baca, S.G.
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856 7 _ |u http://dx.doi.org/10.1021/cg2016337
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