% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Wang:22305,
      author       = {Wang, J. and Näther, C. and Kögerler, P. and Bensch, W.},
      title        = {[{V}15{G}e6{O}42{S}6({H}2{O})]12–, a
                      {T}hiogermanatopolyoxovanadate {C}luster {F}eaturing the
                      {S}pin {T}opology of the {M}olecular {M}agnet
                      [{V}15{A}s6{O}42({H}2{O})]6–},
      journal      = {European journal of inorganic chemistry},
      volume       = {2012},
      number       = {8},
      issn         = {1434-1948},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {PreJuSER-22305},
      pages        = {1237 - 1242},
      year         = {2012},
      note         = {Financial support by the State of Schleswig-Holstein is
                      gratefully acknowledged.},
      abstract     = {The new compound
                      [Co(tren)(trenH(2))](2)[{Co(tren)}(2)-V15Ge6O42S6(H2O)]center
                      dot 9H(2)O [1, tren = tris(2-aminoethyl)amine] has been
                      obtained under solvothermal conditions and features the
                      unique thiogermanatovanadatopolyoxoanion
                      [(V15Ge6O42S6)-Ge-IV-O-IV(H2O)](12-) as the main structural
                      motif. Compound 1 crystallizes in the monoclinic space group
                      P2(1/c) with a = 15.4711(2), b = 26.4031(4), c = 26.7213(4)
                      angstrom, V = 10874.2(3) angstrom(3), and Z = 4. The
                      [V15Ge6O42S6(H2O)](12)- cluster anion displays the spin
                      topology reported for the molecular magnets
                      [(V15As6O42)-As-IV-O-III(H2O)](6-) and
                      [(V15Sb6O42)-Sb-IV-O-III](6-) and therefore represents a new
                      member of the {V15E6} family, which has allowed us to study
                      the magnetic exchange interactions between the vanadyl
                      (d(1)) groups of the geometrically frustrated central V-3
                      triangle, which is sandwiched between strongly
                      antiferromagnetically coupled V-6 hexagons. The cluster
                      shell is expanded by two {Co(tren)}(2+)-based complexes
                      through Co-S bonds, which reduce the high negative charge of
                      the anion. The Co2+ ions in the [Co(tren)(trenH(2))](4+)
                      countercations are coordinated to one tetradentate tren and
                      a monodentate, doubly protonated tren ligand.},
      keywords     = {J (WoSType)},
      cin          = {PGI-6},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-6-20110106},
      pnm          = {Grundlagen für zukünftige Informationstechnologien},
      pid          = {G:(DE-Juel1)FUEK412},
      shelfmark    = {Chemistry, Inorganic $\&$ Nuclear},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000301494000011},
      doi          = {10.1002/ejic.201101187},
      url          = {https://juser.fz-juelich.de/record/22305},
}