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| Hauptseite > Publikationsdatenbank > [V15Ge6O42S6(H2O)]12–, a Thiogermanatopolyoxovanadate Cluster Featuring the Spin Topology of the Molecular Magnet [V15As6O42(H2O)]6– > print |
| Hauptseite > Publikationsdatenbank > [V15Ge6O42S6(H2O)]12–, a Thiogermanatopolyoxovanadate Cluster Featuring the Spin Topology of the Molecular Magnet [V15As6O42(H2O)]6– > print |
| 001 | 22305 | ||
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| 024 | 7 | _ | |2 DOI |a 10.1002/ejic.201101187 |
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| 082 | _ | _ | |a 540 |
| 084 | _ | _ | |2 WoS |a Chemistry, Inorganic & Nuclear |
| 100 | 1 | _ | |a Wang, J. |b 0 |u FZJ |0 P:(DE-Juel1)VDB5805 |
| 245 | _ | _ | |a [V15Ge6O42S6(H2O)]12–, a Thiogermanatopolyoxovanadate Cluster Featuring the Spin Topology of the Molecular Magnet [V15As6O42(H2O)]6– |
| 260 | _ | _ | |a Weinheim |b Wiley-VCH |c 2012 |
| 300 | _ | _ | |a 1237 - 1242 |
| 336 | 7 | _ | |a Journal Article |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |
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| 336 | 7 | _ | |a article |2 DRIVER |
| 440 | _ | 0 | |a European Journal of Inorganic Chemistry |x 1434-1948 |0 11961 |y 8 |
| 500 | _ | _ | |3 POF3_Assignment on 2016-02-29 |
| 500 | _ | _ | |a Financial support by the State of Schleswig-Holstein is gratefully acknowledged. |
| 520 | _ | _ | |a The new compound [Co(tren)(trenH(2))](2)[{Co(tren)}(2)-V15Ge6O42S6(H2O)]center dot 9H(2)O [1, tren = tris(2-aminoethyl)amine] has been obtained under solvothermal conditions and features the unique thiogermanatovanadatopolyoxoanion [(V15Ge6O42S6)-Ge-IV-O-IV(H2O)](12-) as the main structural motif. Compound 1 crystallizes in the monoclinic space group P2(1/c) with a = 15.4711(2), b = 26.4031(4), c = 26.7213(4) angstrom, V = 10874.2(3) angstrom(3), and Z = 4. The [V15Ge6O42S6(H2O)](12)- cluster anion displays the spin topology reported for the molecular magnets [(V15As6O42)-As-IV-O-III(H2O)](6-) and [(V15Sb6O42)-Sb-IV-O-III](6-) and therefore represents a new member of the {V15E6} family, which has allowed us to study the magnetic exchange interactions between the vanadyl (d(1)) groups of the geometrically frustrated central V-3 triangle, which is sandwiched between strongly antiferromagnetically coupled V-6 hexagons. The cluster shell is expanded by two {Co(tren)}(2+)-based complexes through Co-S bonds, which reduce the high negative charge of the anion. The Co2+ ions in the [Co(tren)(trenH(2))](4+) countercations are coordinated to one tetradentate tren and a monodentate, doubly protonated tren ligand. |
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| 653 | 2 | 0 | |2 Author |a Cluster compounds |
| 653 | 2 | 0 | |2 Author |a Solvothermal synthesis |
| 653 | 2 | 0 | |2 Author |a Solid-state structures |
| 653 | 2 | 0 | |2 Author |a Polyoxovanadate |
| 653 | 2 | 0 | |2 Author |a Magnetic properties |
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| 773 | _ | _ | |a 10.1002/ejic.201101187 |g p. 1237 - 1242 |p 1237 - 1242 |q 1237 - 1242 |0 PERI:(DE-600)1475009-0 |t European journal of inorganic chemistry |y 2012 |x 1434-1948 |v 2012 |n 8 |
| 856 | 7 | _ | |u http://dx.doi.org/10.1002/ejic.201101187 |
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