| 001 | 22327 | ||
| 005 | 20180210124815.0 | ||
| 024 | 7 | _ | |2 DOI |a 10.1002/chin.201217015 |
| 024 | 7 | _ | |2 WOS |a WOS:000300466300042 |
| 037 | _ | _ | |a PreJuSER-22327 |
| 041 | _ | _ | |a eng |
| 082 | _ | _ | |a 540 |
| 084 | _ | _ | |2 WoS |a Chemistry, Inorganic & Nuclear |
| 100 | 1 | _ | |a Antonova, E. |b 0 |0 P:(DE-HGF)0 |
| 245 | _ | _ | |a Expansion of Antimonato Polyoxovanadates with Transition Metal Complexes: (Co(N3C5H15)2)2[{Co(N3C5H15)2}V15Sb6O42(H2O)]·5H2O and (Ni(N3C5H15)2)2[{Ni(N3C5H15)2}V15Sb6O42(H2O)]·8H2O |
| 260 | _ | _ | |a Washington, DC |b American Chemical Society |c 2012 |
| 300 | _ | _ | |a 2311 - 2317 |
| 336 | 7 | _ | |a Journal Article |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a article |2 DRIVER |
| 440 | _ | 0 | |a Inorganic Chemistry |x 0020-1669 |0 14061 |y 4 |v 51 |
| 500 | _ | _ | |3 POF3_Assignment on 2016-02-29 |
| 500 | _ | _ | |a Financial support by the State of Schleswig-Holstein is gratefully acknowledged. |
| 520 | _ | _ | |a Two new polyoxovanadates (Co-(N3C5H15)(2))(2)[{ Co(N3C5H15)(2)}V15Sb6O42(H2O)center dot 5H(2)O (1) and (Ni(N3C5H15)(2))(2) [{Ni(N3C5H15)(2)} V15Sb6O42(H2O)]center dot 8H(2)O (2) (N3C5H15 = N-(2-aminoethyl)-1,3-propanediamine) were synthesized under solvothermal conditions and structurally characterized. In both structures the [V15Sb6O42(H2O)](6-) shell displays the main structural motif, which is strongly related to the {V18O42} archetype cluster. Both compounds crystallize in the triclinic space group P (1) over bar with a = 14.3438(4), b = 16.6471(6), c = 18.9186(6) angstrom, alpha = 87.291(3)degrees, beta = 83.340(3)degrees, gamma = 78.890(3)degrees, and V = 4401.4(2) angstrom(3) (1) and a = 14.5697(13), b = 15.8523(16), c = 20.2411(18) angstrom, alpha = 86.702(11)degrees, beta = 84.957(11)degrees, gamma = 76.941(11)degrees, and V = 4533.0(7) angstrom(3) (2). In the structure of 1 the [V15Sb6O42(H2O)](6-) cluster anion is bound to a [Co(N3C5H15)(2)](2+) complex via a terminal oxygen atom. In the Co2+-centered complex, one of the amine ligands coordinates in tridentate mode and the second one in bidentate mode to form a strongly distorted CoN5O octahedron. Similarly, in compound 2 an analogous NiN5O complex is joined to the [V15Sb6O42(H2O)](6-) anion via the same attachment mode. A remarkable difference between the two compounds is the orientation of the noncoordinated propylamine group leading to intermolecular Sb center dot center dot center dot O contacts in 1 and to Sb center dot center dot center dot N interactions in 2. In the solid-state lattices of 1 and 2, two additional [M(N3C5H15)(2)](2+) complexes act as countercations and are located between the [{M(N3C5H15)(2)}V15Sb6O42(H2O)](4-) anions. Between the anions and cations strong N-H center dot center dot center dot O hydrogen bonds are observed. In both compounds the clusters are stacked along the b axis in an ABAB fashion with cations and water molecules occupying the space between the clusters. Magnetic characterization demonstrates that the Ni2+ and Co2+ cations do not significantly couple with the S = 1/2 vanadyl groups. The susceptibility data can be successfully reproduced assuming a distorted ligand field for the Co2+ ions (1) and an O-h-symmetric Ni2+ ligand field (2). |
| 536 | _ | _ | |a Grundlagen für zukünftige Informationstechnologien |c P42 |2 G:(DE-HGF) |0 G:(DE-Juel1)FUEK412 |x 0 |
| 588 | _ | _ | |a Dataset connected to Web of Science |
| 650 | _ | 7 | |a J |2 WoSType |
| 700 | 1 | _ | |a Näther, C. |b 1 |u FZJ |0 P:(DE-Juel1)VDB73208 |
| 700 | 1 | _ | |a Kögerler, P. |b 2 |u FZJ |0 P:(DE-Juel1)VDB12080 |
| 700 | 1 | _ | |a Bensch, W. |b 3 |0 P:(DE-HGF)0 |
| 773 | _ | _ | |a 10.1002/chin.201217015 |g Vol. 43, p. 2311 - 2317 |p 2311 - 2317 |q 43<2311 - 2317 |0 PERI:(DE-600)1484438-2 |t Inorganic chemistry |v 43 |y 2012 |x 0020-1669 |
| 856 | 7 | _ | |u http://dx.doi.org/10.1002/chin.201217015 |
| 909 | C | O | |o oai:juser.fz-juelich.de:22327 |p VDB |
| 913 | 1 | _ | |b Schlüsseltechnologien |k P42 |l Grundlagen für zukünftige Informationstechnologien (FIT) |1 G:(DE-HGF)POF2-420 |0 G:(DE-Juel1)FUEK412 |2 G:(DE-HGF)POF2-400 |v Grundlagen für zukünftige Informationstechnologien |x 0 |
| 913 | 2 | _ | |a DE-HGF |b Key Technologies |l Future Information Technology - Fundamentals, Novel Concepts and Energy Efficiency (FIT) |1 G:(DE-HGF)POF3-520 |0 G:(DE-HGF)POF3-529H |2 G:(DE-HGF)POF3-500 |v Addenda |x 0 |
| 914 | 1 | _ | |y 2012 |
| 915 | _ | _ | |a JCR/ISI refereed |0 StatID:(DE-HGF)0010 |2 StatID |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0110 |2 StatID |b Science Citation Index |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0111 |2 StatID |b Science Citation Index Expanded |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Thomson Reuters Master Journal List |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0310 |2 StatID |b NCBI Molecular Biology Database |
| 915 | _ | _ | |a Nationallizenz |0 StatID:(DE-HGF)0420 |2 StatID |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1040 |2 StatID |b Zoological Record |
| 920 | 1 | _ | |k PGI-6 |l Elektronische Eigenschaften |g PGI |0 I:(DE-Juel1)PGI-6-20110106 |x 0 |
| 970 | _ | _ | |a VDB:(DE-Juel1)138824 |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a ConvertedRecord |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a I:(DE-Juel1)PGI-6-20110106 |
| 980 | _ | _ | |a UNRESTRICTED |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|
guest ::