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@ARTICLE{Liebsch:22344,
author = {Liebsch, A. and Ishida, H.},
title = {{T}emperature and bath size in exact diagonalization
dynamical mean field theory},
journal = {Journal of physics / Condensed matter},
volume = {24},
issn = {0953-8984},
address = {Bristol},
publisher = {IOP Publ.},
reportid = {PreJuSER-22344},
pages = {053201},
year = {2012},
note = {Record converted from VDB: 12.11.2012},
abstract = {Dynamical mean field theory (DMFT), combined with
finite-temperature exact diagonalization, is one of the
methods used to describe electronic properties of strongly
correlated materials. Because of the rapid growth of the
Hilbert space, the size of the finite bath used to represent
the infinite lattice is severely limited. In view of the
increasing interest in the effect of multi-orbital and
multi-site Coulomb correlations in transition metal oxides,
high-T(c) cuprates, iron-based pnictides, organic crystals,
etc, it is appropriate to explore the range of temperatures
and bath sizes in which exact diagonalization provides
accurate results for various system properties. On the one
hand, the bath must be large enough to achieve a
sufficiently dense level spacing, so that useful spectral
information can be derived, especially close to the Fermi
level. On the other hand, for an adequate projection of the
lattice Green's function onto a finite bath, the choice of
the temperature is crucial. The role of these two key
ingredients in exact diagonalization DMFT is discussed for a
wide variety of systems in order to establish the domain of
applicability of this approach. Three criteria are used to
illustrate the accuracy of the results: (i) the convergence
of the self-energy with the bath size, (ii) the quality of
the discretization of the bath Green's function, and (iii)
comparisons with complementary results obtained via
continuous-time quantum Monte Carlo DMFT. The materials
comprise a variety of three-orbital and five-orbital
systems, as well as single-band Hubbard models for
two-dimensional triangular, square and honeycomb lattices,
where non-local Coulomb correlations are important. The main
conclusion from these examples is that a larger number of
correlated orbitals or sites requires a smaller number of
bath levels. Down to temperatures of 5-10 meV (for typical
bandwidths W ≈ 2 eV) two bath levels per correlated
impurity orbital or site are usually adequate.},
keywords = {Algorithms / Calcium: chemistry / Chemistry, Physical:
methods / Cobalt: chemistry / Models, Statistical / Monte
Carlo Method / Oxygen: chemistry / Reproducibility of
Results / Rubidium: chemistry / Sodium: chemistry / Software
/ Temperature / Vanadium: chemistry / Rubidium (NLM
Chemicals) / Sodium (NLM Chemicals) / Cobalt (NLM Chemicals)
/ Vanadium (NLM Chemicals) / Calcium (NLM Chemicals) /
Oxygen (NLM Chemicals) / J (WoSType)},
cin = {IAS-1 / PGI-1},
ddc = {530},
cid = {I:(DE-Juel1)IAS-1-20090406 / I:(DE-Juel1)PGI-1-20110106},
pnm = {Grundlagen für zukünftige Informationstechnologien},
pid = {G:(DE-Juel1)FUEK412},
shelfmark = {Physics, Condensed Matter},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:22156113},
UT = {WOS:000299326500007},
doi = {10.1088/0953-8984/24/5/053201},
url = {https://juser.fz-juelich.de/record/22344},
}