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000022351 084__ $$2WoS$$aChemistry, Inorganic & Nuclear
000022351 1001_ $$0P:(DE-HGF)0$$aOHalloran, K.P.$$b0
000022351 245__ $$aRevisiting the Polyoxometalate-Based Late-Transition-Metal-Oxo Complexes: The "Oxo Wall" Stands
000022351 260__ $$aWashington, DC$$bAmerican Chemical Society$$c2012
000022351 300__ $$a7025 - 7031
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000022351 440_0 $$014061$$aInorganic Chemistry$$v51$$x0020-1669$$y13
000022351 500__ $$3POF3_Assignment on 2016-02-29
000022351 500__ $$aWe thank the National Science Foundation (grant CHE-0911610) for support of this research. We also thank Dr. Ulrich Kortz of Jacobs University (Bremen, Germany) for challenging our work.
000022351 520__ $$aTerminal oxo complexes of the late transition metals Pt, Pd, and Au have been reported by us in Science and Journal of the American Chemical Society. Despite thoroughness in characterizing these complexes (multiple independent structural methods and up to 17 analytical methods in one case), we have continued to study these structures. Initial work on these systems was motivated by structural data from X-ray crystallography and neutron diffraction and (17)O and (31)P NMR signatures which all indicated differences from all previously published compounds. With significant new data, we now revisit these studies. New X-ray crystal structures of previously reported complexes K(14)[P(2)W(19)O(69)(OH(2))] and "K(10)Na(3)[Pd(IV)(O)(OH)WO(OH(2))(PW(9)O(34))(2)]" and a closer examination of these structures are provided. Also presented are the (17)O NMR spectrum of an (17)O-enriched sample of [PW(11)O(39)](7-) and a careful combined (31)P NMR-titration study of the previously reported "K(7)H(2)[Au(O)(OH(2))P(2)W(20)O(70)(OH(2))(2)]." These and considerable other data collectively indicate that previously assigned terminal Pt-oxo and Au-oxo complexes are in fact cocrystals of the all-tungsten structural analogues with noble metal cations, while the Pd-oxo complex is a disordered Pd(II)-substituted polyoxometalate. The neutron diffraction data have been re-analyzed, and new refinements are fully consistent with the all-tungsten formulations of the Pt-oxo and Au-oxo polyoxometalate species.
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000022351 7001_ $$0P:(DE-HGF)0$$aZhao, C.$$b1
000022351 7001_ $$0P:(DE-HGF)0$$aAndo, N.S.$$b2
000022351 7001_ $$0P:(DE-HGF)0$$aSchultz, A.J.$$b3
000022351 7001_ $$0P:(DE-HGF)0$$aKoetzle, T.F.$$b4
000022351 7001_ $$0P:(DE-HGF)0$$aPiccoli, P.M.B.$$b5
000022351 7001_ $$0P:(DE-HGF)0$$aHedman, B.$$b6
000022351 7001_ $$0P:(DE-HGF)0$$aHodgson, K.O.$$b7
000022351 7001_ $$0P:(DE-HGF)0$$aBobyr, E.$$b8
000022351 7001_ $$0P:(DE-HGF)0$$aKirk, M.L.$$b9
000022351 7001_ $$0P:(DE-HGF)0$$aKnottenbelt, S.$$b10
000022351 7001_ $$0P:(DE-HGF)0$$aDepperman, E.C.$$b11
000022351 7001_ $$0P:(DE-HGF)0$$aStein, B.$$b12
000022351 7001_ $$0P:(DE-HGF)0$$aAnderson, T.M.$$b13
000022351 7001_ $$0P:(DE-HGF)0$$aCao, R.$$b14
000022351 7001_ $$0P:(DE-HGF)0$$aGeletii, Y.V.$$b15
000022351 7001_ $$0P:(DE-HGF)0$$aHardcastle, K.I.$$b16
000022351 7001_ $$0P:(DE-HGF)0$$aMusaev, D.G.$$b17
000022351 7001_ $$0P:(DE-HGF)0$$aNeiwert, W.A.$$b18
000022351 7001_ $$0P:(DE-HGF)0$$aFang, X.$$b19
000022351 7001_ $$0P:(DE-HGF)0$$aMorokuma, K.$$b20
000022351 7001_ $$0P:(DE-Juel1)VDB13448$$aWu, S.$$b21$$uFZJ
000022351 7001_ $$0P:(DE-Juel1)VDB12080$$aKögerler, P.$$b22$$uFZJ
000022351 7001_ $$0P:(DE-HGF)0$$aHill, C.L.$$b23
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