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| 001 | 22478 | ||
| 005 | 20180210140941.0 | ||
| 024 | 7 | _ | |2 DOI |a 10.1016/j.ica.2011.08.061 |
| 024 | 7 | _ | |2 WOS |a WOS:000300180100010 |
| 037 | _ | _ | |a PreJuSER-22478 |
| 041 | _ | _ | |a eng |
| 082 | _ | _ | |a 540 |
| 084 | _ | _ | |2 WoS |a Chemistry, Inorganic & Nuclear |
| 100 | 1 | _ | |0 P:(DE-HGF)0 |a Malaestean, I.L. |b 0 |
| 245 | _ | _ | |a Macrocycles based on magnetically functionalized zirconium oxide clusters |
| 260 | _ | _ | |a New York, NY [u.a.] |b Elsevier |c 2012 |
| 300 | _ | _ | |a 72 - 77 |
| 336 | 7 | _ | |a Journal Article |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a article |2 DRIVER |
| 440 | _ | 0 | |0 26383 |a Inorganica Chimica Acta |v 380 |
| 500 | _ | _ | |3 POF3_Assignment on 2016-02-29 |
| 500 | _ | _ | |a Ames Laboratory is operated for the U.S. Department of Energy by Iowa State University under Contract No. DE-AC02-07CH11358. |
| 520 | _ | _ | |a In the presence of 4,4'-bipyridine and Co(II) or Ni(II) groups, which are coordinatively constrained by bis-alkoxyamine chelating groups, dimeric [(Zr6O4)-O-IV(OH)(4)(RCOO)(12)](2) clusters rearrange to {Zr12O11(OH)(11)(RCOO)(16)} frameworks featuring highly condensed zirconium oxide cores. These {Zr-12} groups subsequently each coordinate to three M(II) groups and self-assemble via two bridging 4,4'-bpy into 2.6 nm {M6Zr24}type macrocycles of composition [M6Zr24O22(OH)(22)(C2H5COO)(40)(Hmdea)(2)(H(2)mdea)(4)(4,4'-bpy)(2)]. Surprisingly, two M(II) sites peripherally attached to the {Zr-12} frameworks adopt a rare eightfold coordination mode where the M2+ ions reside in a distorted square antiprismatic O7N environment. Magnetic measurements reveal that the zirconium oxide fragments efficiently mediate antiferromagnetic exchange between Ni2+ spin centers, whereas in case of the virtually isostructural Co2+ derivative pronounced ligand field asymmetry causes single-ion effects to significantly influence the low-field susceptibility data. (C) 2011 Elsevier B. V. All rights reserved. |
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| 588 | _ | _ | |a Dataset connected to Web of Science |
| 650 | _ | 7 | |2 WoSType |a J |
| 653 | 2 | 0 | |2 Author |a Heterometallic complexes |
| 653 | 2 | 0 | |2 Author |a Magnetic properties |
| 653 | 2 | 0 | |2 Author |a Zirconium compounds |
| 653 | 2 | 0 | |2 Author |a Macrocycles |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Kutluca, M. |b 1 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Speldrich, M. |b 2 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Ellern, A. |b 3 |
| 700 | 1 | _ | |0 P:(DE-Juel1)VDB12080 |a Kögerler, P. |b 4 |u FZJ |
| 773 | _ | _ | |0 PERI:(DE-600)1484441-2 |a 10.1016/j.ica.2011.08.061 |g Vol. 380, p. 72 - 77 |p 72 - 77 |q 380<72 - 77 |t Inorganica chimica acta |v 380 |x 0020-1693 |y 2012 |
| 856 | 7 | _ | |u http://dx.doi.org/10.1016/j.ica.2011.08.061 |
| 909 | C | O | |o oai:juser.fz-juelich.de:22478 |p VDB |
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| 914 | 1 | _ | |y 2012 |
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