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000022568 084__ $$2WoS$$aPhysics, Multidisciplinary
000022568 1001_ $$0P:(DE-Juel1)VDB93048$$aStadtmüller, B.$$b0$$uFZJ
000022568 245__ $$aCommensurate registry and chemisorptions at a hetero-organic interface
000022568 260__ $$aCollege Park, Md.$$bAPS$$c2012
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000022568 520__ $$aWe present evidence for a partly chemisorptive bonding between single monolayers of copper-II-phthalocyanine (CuPc) and 3,4,9,10-perylene-tetracarboxylic-dianhydride (PTCDA) that are stacked on Ag(111). A commensurate registry between the two molecular layers and the substrate, i.e., a common crystallographic lattice for CuPc and PTCDA films as well as for the Ag(111) surface, indicates that the growth of the upper layer is dominated by the structure of the lower. Photoemission spectroscopy clearly reveals a gradual filling of the lowest unoccupied molecular orbital of PTCDA due to CuPc adsorption, which proves the chemisorptive character.
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000022568 7001_ $$0P:(DE-Juel1)VDB108559$$aSueyoshi, T.$$b1$$uFZJ
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000022568 7001_ $$0P:(DE-Juel1)VDB73384$$aTemirov, R.$$b5$$uFZJ
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000022568 8567_ $$uhttp://dx.doi.org/10.1103/PhysRevLett.108.106103
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