% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Cao:22659,
      author       = {Cao, Z. and Jiang, H. and Luo, H. and Baumann, S. and
                      Meulenberg, W.A. and Voss, H. and Caro, J.},
      title        = {{S}imultaneous overcome of the equilibrium-limitations in
                      {BSCF} oxygen-permeable membrane reactors: {W}ater splitting
                      and methane coupling},
      journal      = {Catalysis today},
      volume       = {193},
      issn         = {0920-5861},
      address      = {Amsterdam},
      publisher    = {Elsevier},
      reportid     = {PreJuSER-22659},
      pages        = {2 - 7},
      year         = {2012},
      note         = {Financial support from EU through FP7 NASA-OTM project
                      (grant agreement no. 228701) is kindly acknowledged. H. Luo
                      thanks the financial support by the China Scholarship
                      Council (CSC).},
      abstract     = {The equilibrium limitations of water splitting and the
                      coupling of methane to C-2 hydrocarbons (ethane + ethylene)
                      were simultaneously overcome by using a perovskite
                      Ba0.5Sr0.5Co0.8Fe0.2O3-delta (BSCF) oxygen-permeable
                      membrane reactor. Oxygen produced from thermal water
                      splitting was transported through the BSCF membrane and
                      consumed in the coupling of methane. The BSCF membrane
                      consists of an about 70 mu m thick dense BSCF layer on an
                      about 0.8 mm thick porous BSCF layer as support. By applying
                      the membrane reactor concept instead of a fixed bed reactor
                      without oxygen supply, the methane conversion and C-2 yield
                      increased from $3.7\%$ to $26\%$ and $3.1\%$ to $6.5\%$ at
                      950 degrees C, respectively. In both experiments, the
                      supported 2 $wt.\%$ Mn-5 $wt.\%$ Na2WO4 catalyst was used at
                      950 degrees C. Simultaneously, about $9\%$ of the H2O
                      injected was converted to hydrogen with a production rate of
                      about 3.3 cm(3) min(-1) cm(-2) at 950 degrees C which is
                      higher than 1 m(3) (STP) H-2 m(-2)h(-1). (c) 2011 Elsevier
                      B.V. All rights reserved.},
      keywords     = {J (WoSType)},
      cin          = {IEK-1},
      ddc          = {660},
      cid          = {I:(DE-Juel1)IEK-1-20101013},
      pnm          = {Rationelle Energieumwandlung},
      pid          = {G:(DE-Juel1)FUEK402},
      shelfmark    = {Chemistry, Applied / Chemistry, Physical / Engineering,
                      Chemical},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000308675900002},
      doi          = {10.1016/j.cattod.2011.12.018},
      url          = {https://juser.fz-juelich.de/record/22659},
}