000022703 001__ 22703
000022703 005__ 20240619092043.0
000022703 0247_ $$2DOI$$a10.1021/ma3004136
000022703 0247_ $$2WOS$$aWOS:000305661600027
000022703 0247_ $$2MLZ$$adoi:10.1021/ma3004136
000022703 037__ $$aPreJuSER-22703
000022703 041__ $$aeng
000022703 082__ $$a540
000022703 084__ $$2WoS$$aPolymer Science
000022703 1001_ $$0P:(DE-Juel1)VDB97037$$aDi, Z.$$b0$$uFZJ
000022703 245__ $$aStepwise Swelling of a Thin JFilm of Lamellae-Forming Poly(styrene-b-butadiene) in Cyclohexane Vapor
000022703 260__ $$aWashington, DC$$bSoc.$$c2012
000022703 300__ $$a5185 - 5195
000022703 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article
000022703 3367_ $$2DataCite$$aOutput Types/Journal article
000022703 3367_ $$00$$2EndNote$$aJournal Article
000022703 3367_ $$2BibTeX$$aARTICLE
000022703 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000022703 3367_ $$2DRIVER$$aarticle
000022703 440_0 $$04142$$aMacromolecules$$v45$$x0024-9297$$y12
000022703 500__ $$aFinancial support by the Graduate School of Excellence "Materials Science of Complex Interfaces", DANSYNC/DANSCATT, the Chinese Scholarship Council, and The Russian Foundation for Basic Research is gratefully acknowledged. CHESS is supported by NSF/NIH/NIGMS award DMR-0936384.
000022703 520__ $$aWe investigated the swelling of a thin film of lamellae-forming poly(styrene-b-butadiene) in cyclohexane vapor. The vapor pressure and thus the degree of swelling of the film are increased in a stepwise manner using a custom-built sample cell. The resulting structural changes during and after each step were followed in situ using time-resolved grazing-incidence small-angle X-ray scattering (GISAXS). During the first step, the lamellar thickness increases strongly, before it decreases again. At the same time, the full width at half-maximum (FWHM) of the diffuse Bragg reflection along the film normal has a sharp maximum. These observations point to the formation of new lamellae. During the subsequent swelling steps, the lamellar thickness overshoots only weakly. The behavior thus resembles qualitatively our previous results on a similar thin film during swelling in saturated vapor of cyclohexane; however, it deviates from earlier theoretical predictions. We propose a theory that is quantitatively correct for the description of the dependence of the lamellar thickness on the polymer volume fraction in the late stage of the swelling steps.
000022703 536__ $$0G:(DE-Juel1)FUEK505$$2G:(DE-HGF)$$aBioSoft: Makromolekulare Systeme und biologische Informationsverarbeitung (FUEK505)$$cFUEK505$$x0
000022703 536__ $$0G:(DE-HGF)POF2-544$$a544 - In-house Research with PNI (POF2-544)$$cPOF2-544$$fPOF II$$x1
000022703 588__ $$aDataset connected to Web of Science
000022703 650_7 $$2WoSType$$aJ
000022703 65027 $$0V:(DE-MLZ)SciArea-210$$2V:(DE-HGF)$$aSoft Condensed Matter$$x0
000022703 65017 $$0V:(DE-MLZ)GC-1602-2016$$2V:(DE-HGF)$$aPolymers, Soft Nano Particles and  Proteins$$x1
000022703 65017 $$0V:(DE-MLZ)GC-150-1$$2V:(DE-HGF)$$aKey Technologies$$x0
000022703 693__ $$0EXP:(DE-MLZ)External-20140101$$5EXP:(DE-MLZ)External-20140101$$eExternal Measurement$$x0
000022703 7001_ $$0P:(DE-HGF)0$$aPosselt, D.$$b1
000022703 7001_ $$0P:(DE-HGF)0$$aSmilgies, D.-M.$$b2
000022703 7001_ $$0P:(DE-HGF)0$$aLi, R.$$b3
000022703 7001_ $$0P:(DE-HGF)0$$aRauscher, M.$$b4
000022703 7001_ $$0P:(DE-HGF)0$$aPotemkin, I.I.$$b5
000022703 7001_ $$0P:(DE-HGF)0$$aPapadakis, C.M.$$b6
000022703 773__ $$0PERI:(DE-600)1491942-4$$a10.1021/ma3004136$$gVol. 45, p. 5185 - 5195$$p5185 - 5195$$q45<5185 - 5195$$tMacromolecules$$v45$$x0024-9297$$y2012
000022703 8567_ $$uhttp://dx.doi.org/10.1021/ma3004136
000022703 909CO $$ooai:juser.fz-juelich.de:22703$$pVDB$$pVDB:MLZ
000022703 915__ $$0StatID:(DE-HGF)0010$$2StatID$$aJCR/ISI refereed
000022703 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR
000022703 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index
000022703 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000022703 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000022703 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bThomson Reuters Master Journal List
000022703 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS
000022703 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000022703 915__ $$0StatID:(DE-HGF)0310$$2StatID$$aDBCoverage$$bNCBI Molecular Biology Database
000022703 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz
000022703 915__ $$0StatID:(DE-HGF)1040$$2StatID$$aDBCoverage$$bZoological Record
000022703 9141_ $$y2012
000022703 9132_ $$0G:(DE-HGF)POF3-551$$1G:(DE-HGF)POF3-550$$2G:(DE-HGF)POF3-500$$aDE-HGF$$bKey Technologies$$lBioSoft  Fundamentals for future Technologies in the fields of Soft Matter and Life Sciences$$vFunctional Macromolecules and Complexes$$x0
000022703 9132_ $$0G:(DE-HGF)POF3-623$$1G:(DE-HGF)POF3-620$$2G:(DE-HGF)POF3-600$$aDE-HGF$$bForschungsbereich Materie$$lIn-house research on the structure, dynamics and function of matter$$vNeutrons for Research on Condensed Matter$$x1
000022703 9131_ $$0G:(DE-HGF)POF2-544$$1G:(DE-HGF)POF2-540$$2G:(DE-HGF)POF2-500$$3G:(DE-HGF)POF2$$4G:(DE-HGF)POF$$aDE-HGF$$bStruktur der Materie$$lForschung mit Photonen, Neutronen, Ionen$$vIn-house Research with PNI$$x0
000022703 9201_ $$0I:(DE-Juel1)ICS-1-20110106$$gICS$$kICS-1$$lNeutronenstreuung$$x0
000022703 9201_ $$0I:(DE-Juel1)JCNS-FRM-II-20110218$$kJCNS (München) ; Jülich Centre for Neutron Science JCNS (München) ; JCNS-FRM-II$$lJCNS-FRM-II$$x1
000022703 9201_ $$0I:(DE-Juel1)JCNS-1-20110106$$gJCNS$$kJCNS-1$$lNeutronenstreuung$$x2
000022703 970__ $$aVDB:(DE-Juel1)139411
000022703 980__ $$aVDB
000022703 980__ $$aConvertedRecord
000022703 980__ $$ajournal
000022703 980__ $$aI:(DE-Juel1)ICS-1-20110106
000022703 980__ $$aI:(DE-Juel1)JCNS-FRM-II-20110218
000022703 980__ $$aI:(DE-Juel1)JCNS-1-20110106
000022703 980__ $$aUNRESTRICTED
000022703 981__ $$aI:(DE-Juel1)IBI-8-20200312
000022703 981__ $$aI:(DE-Juel1)JCNS-1-20110106
000022703 981__ $$aI:(DE-Juel1)JCNS-FRM-II-20110218