000023105 001__ 23105
000023105 005__ 20240712101032.0
000023105 0247_ $$2DOI$$a10.5194/acp-12-1483-2012
000023105 0247_ $$2WOS$$aWOS:000300656500016
000023105 0247_ $$2Handle$$a2128/7611
000023105 037__ $$aPreJuSER-23105
000023105 041__ $$aeng
000023105 082__ $$a550
000023105 084__ $$2WoS$$aMeteorology & Atmospheric Sciences
000023105 1001_ $$0P:(DE-HGF)0$$aMüller, L.$$b0
000023105 245__ $$aFormation of 3-methyl-1,2,3-butanetricarboxylic acid via gas phase oxidation of pinonic acid - a mass spectrometric study of SOA aging
000023105 260__ $$aKatlenburg-Lindau$$bEGU$$c2012
000023105 300__ $$a1483 - 1496
000023105 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article
000023105 3367_ $$2DataCite$$aOutput Types/Journal article
000023105 3367_ $$00$$2EndNote$$aJournal Article
000023105 3367_ $$2BibTeX$$aARTICLE
000023105 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000023105 3367_ $$2DRIVER$$aarticle
000023105 440_0 $$09601$$aAtmospheric Chemistry and Physics$$v12$$x1680-7316$$y3
000023105 500__ $$3POF3_Assignment on 2016-02-29
000023105 500__ $$aWe thank the AIDA team at KIT for their effective support during the measurement campaign and the EUROCHAMP-2 project within the EC 7th framework programme for financial support.
000023105 520__ $$aThis paper presents the results of mass spectrometric investigations of the OH-initiated oxidative aging of alpha-pinene SOA under simulated tropospheric conditions at the large aerosol chamber facility AIDA, Karlsruhe Institute of Technology. In particular, the OH-initiated oxidation of pure pinic and pinonic acid, two well-known oxidation products of alpha-pinene, was investigated. Two complementary analytical techniques were used, on-line atmospheric pressure chemical ionization/mass spectrometry (APCI/MS) and filter sampling followed by liquid chromatography/mass spectrometry (LC/ESI-MS). The results show that 3-methyl-1,2,3-butanetricarboxylic acid (MBTCA), a very low volatile alpha-pinene SOA product and a tracer compound for terpene SOA, is formed from the oxidation of pinonic acid and that this oxidation takes place in the gas phase. This finding is confirmed by temperature-dependent aging experiments on whole SOA formed from alpha-pinene, in which the yield of MBTCA scales with the pinonic acid fraction in the gas phase. Based on the results, several feasible gas-phase radical mechanisms are discussed to explain the formation of MBTCA from OH-initiated pinonic acid oxidation.
000023105 536__ $$0G:(DE-Juel1)FUEK491$$2G:(DE-HGF)$$aAtmosphäre und Klima$$cP23$$x0
000023105 588__ $$aDataset connected to Web of Science
000023105 650_7 $$2WoSType$$aJ
000023105 7001_ $$0P:(DE-HGF)0$$aReinnig, M.C.$$b1
000023105 7001_ $$0P:(DE-HGF)0$$aNaumann, K.H.$$b2
000023105 7001_ $$0P:(DE-HGF)0$$aSaathoff, H.$$b3
000023105 7001_ $$0P:(DE-Juel1)16346$$aMentel, T.F.$$b4$$uFZJ
000023105 7001_ $$0P:(DE-HGF)0$$aDonahue, N.M.$$b5
000023105 7001_ $$0P:(DE-HGF)0$$aHoffmann, T.$$b6
000023105 773__ $$0PERI:(DE-600)2069847-1$$a10.5194/acp-12-1483-2012$$gVol. 12, p. 1483 - 1496$$p1483 - 1496$$q12<1483 - 1496$$tAtmospheric chemistry and physics$$v12$$x1680-7316$$y2012
000023105 8567_ $$uhttp://dx.doi.org/10.5194/acp-12-1483-2012
000023105 8564_ $$uhttps://juser.fz-juelich.de/record/23105/files/FZJ-23105.pdf$$yOpenAccess$$zPublished final document.
000023105 8564_ $$uhttps://juser.fz-juelich.de/record/23105/files/FZJ-23105.jpg?subformat=icon-1440$$xicon-1440$$yOpenAccess
000023105 8564_ $$uhttps://juser.fz-juelich.de/record/23105/files/FZJ-23105.jpg?subformat=icon-180$$xicon-180$$yOpenAccess
000023105 8564_ $$uhttps://juser.fz-juelich.de/record/23105/files/FZJ-23105.jpg?subformat=icon-640$$xicon-640$$yOpenAccess
000023105 909CO $$ooai:juser.fz-juelich.de:23105$$pdnbdelivery$$pVDB$$pVDB:Earth_Environment$$pdriver$$popen_access$$popenaire
000023105 9131_ $$0G:(DE-Juel1)FUEK491$$1G:(DE-HGF)POF2-230$$2G:(DE-HGF)POF2-200$$bErde und Umwelt$$kP23$$lAtmosphäre und Klima$$vAtmosphäre und Klima$$x0$$zvormals P22
000023105 9132_ $$0G:(DE-HGF)POF3-249H$$1G:(DE-HGF)POF3-240$$2G:(DE-HGF)POF3-200$$aDE-HGF$$bMarine, Küsten- und Polare Systeme$$lAtmosphäre und Klima$$vAddenda$$x0
000023105 9141_ $$y2012
000023105 915__ $$0LIC:(DE-HGF)CCBY3$$2HGFVOC$$aCreative Commons Attribution CC BY 3.0
000023105 915__ $$0StatID:(DE-HGF)0010$$2StatID$$aJCR/ISI refereed
000023105 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR
000023105 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index
000023105 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000023105 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000023105 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bThomson Reuters Master Journal List
000023105 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS
000023105 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000023105 915__ $$0StatID:(DE-HGF)0500$$2StatID$$aDBCoverage$$bDOAJ
000023105 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000023105 915__ $$0StatID:(DE-HGF)1020$$2StatID$$aDBCoverage$$bCurrent Contents - Social and Behavioral Sciences
000023105 9201_ $$0I:(DE-Juel1)IEK-8-20101013$$gIEK$$kIEK-8$$lTroposphäre$$x0
000023105 970__ $$aVDB:(DE-Juel1)140011
000023105 9801_ $$aFullTexts
000023105 980__ $$aVDB
000023105 980__ $$aConvertedRecord
000023105 980__ $$ajournal
000023105 980__ $$aI:(DE-Juel1)IEK-8-20101013
000023105 980__ $$aUNRESTRICTED
000023105 980__ $$aJUWEL
000023105 980__ $$aFullTexts
000023105 981__ $$aI:(DE-Juel1)ICE-3-20101013