Home > Publications database > Formation of 3-methyl-1,2,3-butanetricarboxylic acid via gas phase oxidation of pinonic acid - a mass spectrometric study of SOA aging > print

001     23105
005     20240712101032.0
024 7 _ |a 10.5194/acp-12-1483-2012
|2 DOI
024 7 _ |a WOS:000300656500016
|2 WOS
024 7 _ |a 2128/7611
|2 Handle
037 _ _ |a PreJuSER-23105
041 _ _ |a eng
082 _ _ |a 550
084 _ _ |2 WoS
|a Meteorology & Atmospheric Sciences
100 1 _ |a Müller, L.
|b 0
|0 P:(DE-HGF)0
245 _ _ |a Formation of 3-methyl-1,2,3-butanetricarboxylic acid via gas phase oxidation of pinonic acid - a mass spectrometric study of SOA aging
260 _ _ |a Katlenburg-Lindau
|b EGU
|c 2012
300 _ _ |a 1483 - 1496
336 7 _ |a Journal Article
|0 PUB:(DE-HGF)16
|2 PUB:(DE-HGF)
336 7 _ |a Output Types/Journal article
|2 DataCite
336 7 _ |a Journal Article
|0 0
|2 EndNote
336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a article
|2 DRIVER
440 _ 0 |a Atmospheric Chemistry and Physics
|x 1680-7316
|0 9601
|y 3
|v 12
500 _ _ |3 POF3_Assignment on 2016-02-29
500 _ _ |a We thank the AIDA team at KIT for their effective support during the measurement campaign and the EUROCHAMP-2 project within the EC 7th framework programme for financial support.
520 _ _ |a This paper presents the results of mass spectrometric investigations of the OH-initiated oxidative aging of alpha-pinene SOA under simulated tropospheric conditions at the large aerosol chamber facility AIDA, Karlsruhe Institute of Technology. In particular, the OH-initiated oxidation of pure pinic and pinonic acid, two well-known oxidation products of alpha-pinene, was investigated. Two complementary analytical techniques were used, on-line atmospheric pressure chemical ionization/mass spectrometry (APCI/MS) and filter sampling followed by liquid chromatography/mass spectrometry (LC/ESI-MS). The results show that 3-methyl-1,2,3-butanetricarboxylic acid (MBTCA), a very low volatile alpha-pinene SOA product and a tracer compound for terpene SOA, is formed from the oxidation of pinonic acid and that this oxidation takes place in the gas phase. This finding is confirmed by temperature-dependent aging experiments on whole SOA formed from alpha-pinene, in which the yield of MBTCA scales with the pinonic acid fraction in the gas phase. Based on the results, several feasible gas-phase radical mechanisms are discussed to explain the formation of MBTCA from OH-initiated pinonic acid oxidation.
536 _ _ |a Atmosphäre und Klima
|c P23
|2 G:(DE-HGF)
|0 G:(DE-Juel1)FUEK491
|x 0
588 _ _ |a Dataset connected to Web of Science
650 _ 7 |a J
|2 WoSType
700 1 _ |a Reinnig, M.C.
|b 1
|0 P:(DE-HGF)0
700 1 _ |a Naumann, K.H.
|b 2
|0 P:(DE-HGF)0
700 1 _ |a Saathoff, H.
|b 3
|0 P:(DE-HGF)0
700 1 _ |a Mentel, T.F.
|b 4
|u FZJ
|0 P:(DE-Juel1)16346
700 1 _ |a Donahue, N.M.
|b 5
|0 P:(DE-HGF)0
700 1 _ |a Hoffmann, T.
|b 6
|0 P:(DE-HGF)0
773 _ _ |a 10.5194/acp-12-1483-2012
|g Vol. 12, p. 1483 - 1496
|p 1483 - 1496
|q 12<1483 - 1496
|0 PERI:(DE-600)2069847-1
|t Atmospheric chemistry and physics
|v 12
|y 2012
|x 1680-7316
856 7 _ |u http://dx.doi.org/10.5194/acp-12-1483-2012
856 4 _ |u https://juser.fz-juelich.de/record/23105/files/FZJ-23105.pdf
|y OpenAccess
|z Published final document.
856 4 _ |u https://juser.fz-juelich.de/record/23105/files/FZJ-23105.jpg?subformat=icon-1440
|x icon-1440
|y OpenAccess
856 4 _ |u https://juser.fz-juelich.de/record/23105/files/FZJ-23105.jpg?subformat=icon-180
|x icon-180
|y OpenAccess
856 4 _ |u https://juser.fz-juelich.de/record/23105/files/FZJ-23105.jpg?subformat=icon-640
|x icon-640
|y OpenAccess
909 C O |o oai:juser.fz-juelich.de:23105
|p openaire
|p open_access
|p driver
|p VDB:Earth_Environment
|p VDB
|p dnbdelivery
913 1 _ |b Erde und Umwelt
|k P23
|l Atmosphäre und Klima
|1 G:(DE-HGF)POF2-230
|0 G:(DE-Juel1)FUEK491
|2 G:(DE-HGF)POF2-200
|v Atmosphäre und Klima
|x 0
|z vormals P22
913 2 _ |a DE-HGF
|b Marine, Küsten- und Polare Systeme
|l Atmosphäre und Klima
|1 G:(DE-HGF)POF3-240
|0 G:(DE-HGF)POF3-249H
|2 G:(DE-HGF)POF3-200
|v Addenda
|x 0
914 1 _ |y 2012
915 _ _ |a Creative Commons Attribution CC BY 3.0
|0 LIC:(DE-HGF)CCBY3
|2 HGFVOC
915 _ _ |a JCR/ISI refereed
|0 StatID:(DE-HGF)0010
|2 StatID
915 _ _ |a JCR
|0 StatID:(DE-HGF)0100
|2 StatID
915 _ _ |a WoS
|0 StatID:(DE-HGF)0110
|2 StatID
|b Science Citation Index
915 _ _ |a WoS
|0 StatID:(DE-HGF)0111
|2 StatID
|b Science Citation Index Expanded
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0150
|2 StatID
|b Web of Science Core Collection
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0199
|2 StatID
|b Thomson Reuters Master Journal List
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0200
|2 StatID
|b SCOPUS
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0300
|2 StatID
|b Medline
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0500
|2 StatID
|b DOAJ
915 _ _ |a OpenAccess
|0 StatID:(DE-HGF)0510
|2 StatID
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)1020
|2 StatID
|b Current Contents - Social and Behavioral Sciences
920 1 _ |k IEK-8
|l Troposphäre
|g IEK
|0 I:(DE-Juel1)IEK-8-20101013
|x 0
970 _ _ |a VDB:(DE-Juel1)140011
980 1 _ |a FullTexts
980 _ _ |a VDB
980 _ _ |a ConvertedRecord
980 _ _ |a journal
980 _ _ |a I:(DE-Juel1)IEK-8-20101013
980 _ _ |a UNRESTRICTED
980 _ _ |a JUWEL
980 _ _ |a FullTexts
981 _ _ |a I:(DE-Juel1)ICE-3-20101013

LibraryCollectionCLSMajorCLSMinorLanguageAuthor
Marc 21