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@ARTICLE{Buitenhuis:23307,
      author       = {Buitenhuis, J.},
      title        = {{E}lectrophoresis of fd-virus particles: {E}xperiments and
                      an analysis of the effect of finite rod lengths},
      journal      = {Langmuir},
      volume       = {28},
      issn         = {0743-7463},
      address      = {Washington, DC},
      publisher    = {ACS Publ.},
      reportid     = {PreJuSER-23307},
      pages        = {13354 - 13363},
      year         = {2012},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {The electrophoretic mobility of rodlike fd viruses is
                      measured and compared to theory, with the theoretical
                      calculations performed according to Stigter (Stigter, D.
                      Charged Colloidal Cylinder with a Gouy Double-Layer. J.
                      Colloid Interface Sci. 1975, 53, 296-306. Stigter, D.
                      Electrophoresis of Highly Charged Colloidal Cylinders in
                      Univalent Salt- Solutions. 1. Mobility in Transverse Field.
                      J. Phys. Chem. 1978, 82, 1417-1423. Stigter, D.
                      Electrophoresis of Highly Charged Colloidal Cylinders in
                      Univalent Salt Solutions. 2. Random Orientation in External
                      Field and Application to Polyelectrolytes. J. Phys. Chem.
                      1978, 82, 1424-1429. Stigter, D. Theory of Conductance of
                      Colloidal Electrolytes in Univalent Salt Solutions. J. Phys.
                      Chem. 1979, 83, 1663-1670), who describes the
                      electrophoretic mobility of infinite cylinders including
                      relaxation effects. Using the dissociation constants of the
                      ionizable groups on the surfaces of the fd viruses, we can
                      calculate the mobility without any adjustable parameter
                      (apart from the possible Stern layer thickness). In
                      addition, the approximation in the theoretical description
                      of Stigter (and others) of using a model of infinitely long
                      cylinders, which consequently is independent of the aspect
                      ratio, is examined by performing more elaborate numerical
                      calculations for finite cylinders. It is shown that,
                      although the electrophoretic mobility of cylindrical
                      particles in the limit of low ionic strength depends on the
                      aspect ratio much more than "end effects", at moderate and
                      high ionic strengths the finite and infinite cylinder models
                      differ only to a degree that can be attributed to end
                      effects. Furthermore, the range of validity of the Stokes
                      regime is systematically calculated.},
      keywords     = {J (WoSType)},
      cin          = {ICS-3},
      ddc          = {670},
      cid          = {I:(DE-Juel1)ICS-3-20110106},
      pnm          = {BioSoft: Makromolekulare Systeme und biologische
                      Informationsverarbeitung},
      pid          = {G:(DE-Juel1)FUEK505},
      shelfmark    = {Chemistry, Multidisciplinary / Chemistry, Physical /
                      Materials Science, Multidisciplinary},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:22958165},
      UT           = {WOS:000308787700028},
      doi          = {10.1021/la302245x},
      url          = {https://juser.fz-juelich.de/record/23307},
}