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@ARTICLE{Wang:23329,
      author       = {Wang, Z. and Kriegs, H. and Wiegand, S.},
      title        = {{T}hermal {D}iffusion of {N}ucleotides},
      journal      = {The journal of physical chemistry / B},
      volume       = {116},
      issn         = {1520-6106},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {PreJuSER-23329},
      pages        = {7463 - 7469},
      year         = {2012},
      note         = {We appreciate many fruitful discussions with Dieter Braun
                      and Pablo Blanco. We express our gratitude to Jan Dhont for
                      his generous support. We thank Sabine Willbold for
                      performing the NMR measurements and Doris Vollmer for her
                      help with the micro calorimetry experiments. Financial
                      support due to the Deutsche Forschungsgemeinschaft Grant Wi
                      1684 is gratefully acknowledged.},
      abstract     = {We investigate the thermal diffusion behavior of aqueous
                      solutions of nucleotides using an infrared thermal diffusion
                      forced Rayleigh scattering (IR-TDFRS) setup. In this work we
                      study 5 nucleotides: cyclic nucleotides adenosine and
                      guanosine monophosphate, 5'-adenosine and 5'-cytidine
                      monophosphate, and also adenosine diphosphate in water. The
                      structures of nucleotides vary systematically, which results
                      in different physical properties such as acidity,
                      solubility, hydrophobicity, and melting point. We discuss
                      the connection between the thermal diffusion behavior and
                      the properties of the different nucleotides. Additionally,
                      as in the case of the alkanes and monoscaccharides, we find
                      a correlation between the thermal diffusion coefficient and
                      the ratio of the thermal expansion coefficient and the
                      kinematic viscosity.},
      keywords     = {Nucleotides: chemistry / Thermal Diffusion / Thermodynamics
                      / Water: chemistry / Nucleotides (NLM Chemicals) / Water
                      (NLM Chemicals) / J (WoSType)},
      cin          = {ICS-3},
      ddc          = {530},
      cid          = {I:(DE-Juel1)ICS-3-20110106},
      pnm          = {BioSoft: Makromolekulare Systeme und biologische
                      Informationsverarbeitung},
      pid          = {G:(DE-Juel1)FUEK505},
      shelfmark    = {Chemistry, Physical},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:22663072},
      UT           = {WOS:000305769700009},
      doi          = {10.1021/jp3032644},
      url          = {https://juser.fz-juelich.de/record/23329},
}