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@ARTICLE{Nagy:23898,
author = {Nagy, G. M. and Mayer, D. and Wandlowski, T.},
title = {{D}istance tunnelling characteristics of solid/liquid
interfaces : {A}u(111)/{C}u2 /{H}2{SO}4},
journal = {PhysChemComm},
volume = {5},
issn = {1460-2733},
address = {Cambridge},
publisher = {Royal Society of Chemistry},
reportid = {PreJuSER-23898},
pages = {112 - 116},
year = {2002},
note = {Record converted from VDB: 12.11.2012},
abstract = {This study examined the liquid part of solid/liquid
interfaces at the atomic level. By measuring distance
tunnelling characteristics the height of the potential
barrier between the tip and the sample, i.e., the potential
energy field the tunnelling electrons are exposed to, can be
obtained, and this provides direct access to double layer
properties. We found exponential IS-characteristics for the
bare and the oxidised Au(111) surface, while non-exponential
behaviour was obtained in the presence of ordered adlayers.
The influence of the local environment just within the
Helmholtz layer is strong enough to perturb the tunnelling
process significantly. The electrolyte properties in the
Gouy region do not change with electrode potential, the
liquid in the tunnelling gap has only an average effect by
lowering the barrier height.},
keywords = {J (WoSType)},
cin = {ISG-2 / ISG-3},
ddc = {540},
cid = {I:(DE-Juel1)VDB42 / I:(DE-Juel1)VDB43},
pnm = {Materialien, Prozesse und Bauelemente für die Mikro- und
Nanoelektronik / Kondensierte Materie},
pid = {G:(DE-Juel1)FUEK252 / G:(DE-Juel1)FUEK242},
shelfmark = {Chemistry, Physical},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000178053400001},
doi = {10.1039/b205720b},
url = {https://juser.fz-juelich.de/record/23898},
}