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024 7 _ |2 DOI
|a 10.1016/S0045-6535(02)00191-1
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|a WOS:000178062800008
037 _ _ |a PreJuSER-23904
041 _ _ |a eng
082 _ _ |a 333.7
084 _ _ |2 WoS
|a Environmental Sciences
100 1 _ |a Koo Lee, S. A.
|b 0
|0 P:(DE-HGF)0
245 _ _ |a Long-term fate of the herbicide cinosulfuron in lysimeters planted with rice over four consecutive years
260 _ _ |a Amsterdam [u.a.]
|b Elsevier Science
|c 2002
300 _ _ |a 173 - 181
336 7 _ |a Journal Article
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336 7 _ |a Journal Article
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336 7 _ |a ARTICLE
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336 7 _ |a JOURNAL_ARTICLE
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336 7 _ |a article
|2 DRIVER
440 _ 0 |a Chemosphere
|x 0045-6535
|0 1228
|v 49
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a in order to elucidate the long-term fate of the sulfonylurea herbicide cinosulfuron, the C-14-labelled chemical was applied to a clay loam soil, encased in two lysimeters, 22 days after rice (Oryza sativa L.) transplanting, and rice plants were grown for four consecutive years. Throughout the experimental period, leaching through soil profiles, absorption and translocation by rice plants, and distribution of C-14 by downward movement in the soil layers were clarified. The total volume of leachates collected through the lysimeter soil over the four years amounted to 168 and 146 L in lysimeters I and 11, respectively. The leachates contained 2.43% and 2.99% of the originally applied C-14-radioactivity, corresponding to an average concentration of 0.29 and 0.41 mug/L as the cinosulfuron equivalent in lysimeters I and II, respectively. The total C-14-radioactivity translocated to rice plants in the third and fourth year was 0.69% and 0.60% (lysimeter 1), and 1.02% and 0.84% (lysimeter 11) of the C-14 applied, respectively. Larger amounts of cinosulfuron equivalents (0.54-0.75%) remained in the straw in the fourth year than in any other parts. The C-14-radioactivities distributed down to a depth of 70 cm after four years were 56.71-57.52% of the C-14 applied, indicating the continuous downward movement and degradation of cinosulfuron in soil. The non-extractable residues were more than 88% of the soil radioactivity and some 45-48% of them was incorporated into the humin fraction. The C-14-radioactivity partitioned into the aqueous phase was nearly 30% of the extractable 14C, suggesting strongly that cinosulfuron was degraded into some polar products during the experimental period. It was found out in a supplemental investigation that flooding and constant higher temperature enhanced mineralization of [C-14]cinosulfuron to (CO2)-C-14 in soil, indicating the possibility of chemical hydrolysis and microbial degradation of the compound in the flooded lysimeter soil. (C) 2002 Published by Elsevier Science Ltd.
536 _ _ |a Chemie und Dynamik der Geo-Biosphäre
|c U01
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588 _ _ |a Dataset connected to Web of Science
650 _ 7 |a J
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653 2 0 |2 Author
|a sulfonylurea herbicide
653 2 0 |2 Author
|a C-14-cinosulfuron
653 2 0 |2 Author
|a lysimeter
653 2 0 |2 Author
|a leaching
653 2 0 |2 Author
|a degradation
700 1 _ |a Führ, F.
|b 1
|u FZJ
|0 P:(DE-Juel1)VDB428
700 1 _ |a Wook Kwon, J.
|b 2
|0 P:(DE-HGF)0
700 1 _ |a Chang Ahn, K.
|b 3
|0 P:(DE-HGF)0
773 _ _ |a 10.1016/S0045-6535(02)00191-1
|g Vol. 49, p. 173 - 181
|p 173 - 181
|q 49<173 - 181
|0 PERI:(DE-600)1496851-4
|t Chemosphere
|v 49
|y 2002
|x 0045-6535
909 C O |o oai:juser.fz-juelich.de:23904
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913 1 _ |k U01
|v Chemie und Dynamik der Geo-Biosphäre
|l Chemie und Dynamik der Geo-Biosphäre
|b Environment (Umwelt)
|0 G:(DE-Juel1)FUEK257
|x 0
914 1 _ |y 2002
915 _ _ |0 StatID:(DE-HGF)0010
|a JCR/ISI refereed
920 1 _ |k ICG-IV
|l Agrosphäre
|d 31.12.2006
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|0 I:(DE-Juel1)VDB50
|x 0
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980 _ _ |a UNRESTRICTED
981 _ _ |a I:(DE-Juel1)IBG-3-20101118


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