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@ARTICLE{vonHobe:2552,
      author       = {von Hobe, M. and Stroh, F. and Beckers, H. and Benter, T.
                      and Willner, H.},
      title        = {{T}he {UV}/{V}is absorption spectrum of matrix isolated
                      dichlorine peroxide, {C}l{OOC}l},
      journal      = {Physical Chemistry Chemical Physics},
      volume       = {11},
      issn         = {1463-9076},
      address      = {Cambridge},
      publisher    = {RSC Publ.},
      reportid     = {PreJuSER-2552},
      pages        = {1571 - 1580},
      year         = {2009},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {UV/Vis absorption spectra of ClOOCl isolated in neon
                      matrices were measured in the wavelength range 220-400 nm.
                      The purity of the trapped samples was checked by infrared
                      and UV/Vis matrix spectroscopy as well as low-temperature
                      Raman spectroscopy. At wavelengths below 290 nm, the results
                      agree with the UV spectrum recently published by Pope et al.
                      [J. Phys. Chem. A, 2007, 111, 4322-4332]. However, the
                      observed absorption in the long wavelength tail of the
                      spectrum-relevant for polar stratospheric ozone loss-is
                      substantially higher than reported by Pope et al. Our
                      results suggest the existence of a ClOOCl electronic state
                      manifold leading to an absorption band similar to those of
                      the near UV spectrum of Cl(2). The differences to previous
                      studies can be accounted for quantitatively by contributions
                      to the reported absorption spectra caused by impurities. The
                      observed band in the long wavelength tail is supported by
                      several high-level ab initio calculations. However,
                      questions arise concerning absolute values of the ClOOCl
                      cross sections, an issue that needs to be revisited in
                      future studies. With calculated photolysis rates based on
                      our spectrum scaled to previous cross sections at the peak
                      absorption, the known polar catalytic ozone-destruction
                      cycles to a large extent account for the observed ozone
                      depletion in the spring polar stratosphere.},
      keywords     = {J (WoSType)},
      cin          = {ICG-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)VDB790},
      pnm          = {Atmosphäre und Klima},
      pid          = {G:(DE-Juel1)FUEK406},
      shelfmark    = {Chemistry, Physical / Physics, Atomic, Molecular $\&$
                      Chemical},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:19240934},
      UT           = {WOS:000263837200012},
      doi          = {10.1039/b814373k},
      url          = {https://juser.fz-juelich.de/record/2552},
}