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@ARTICLE{Palisaitis:255479,
author = {Palisaitis, Justinas and Ivanova, Mariya and Meulenberg,
Wilhelm A. and Guillon, Olivier and Mayer, Joachim},
title = {{P}hase homogeneity analysis of
{L}a$_{0.99}${S}r$_{0.01}${N}b$_{0.99}${A}l$_{0.01}${O}$_{4−δ}$
and
{L}a$_{0.99}${C}a$_{0.01}${N}b$_{0.99}${T}i$_{0.01}${O}$_{4−δ}$
proton conductors by high-resolution {STEM} and {EELSK}},
journal = {Journal of the European Ceramic Society},
volume = {35},
number = {5},
issn = {0955-2219},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {FZJ-2015-05641},
pages = {1517 - 1525},
year = {2015},
abstract = {The microstructural and compositional homogeneity of
La0.99Ca0.01Nb0.99Ti0.01O4−δ and
La0.99Sr0.01Nb0.99Al0.01O4−δ proton conductors was
studied using the combination of atomic-resolution scanning
transmission electron microscopy (STEM), electron energy
loss spectroscopy (EELS) and STEM image simulations. The
obtained results revealed that gently doped proton
conductors were predominantly composed of grains with a
monoclinic lanthanum niobate crystal structure. In addition
to the host phase, dopant-rich phases were also observed and
identified. The La0.99Sr0.01Nb0.99Al0.01O4−δ matrix
accommodated dopant-rich grains retaining an LaAlO3 cubic
crystal structure with a significant fraction of Sr
incorporated into them. The secondary phases embedded in the
La0.99Ca0.01Nb0.99Ti0.01O4−δ matrix possessed the
pyrochlore La2Ti2O7 crystal structure with Ca partially
substituting La. High spatial resolution EELS revealed
preferential Ca sites within the pyrochlore La2Ti2O7 crystal
lattice. The origin of the secondary phase formation and the
role of these phases for the transport properties of
co-doped lanthanum niobates are discussed here.},
cin = {IEK-1 / JARA-ENERGY},
ddc = {660},
cid = {I:(DE-Juel1)IEK-1-20101013 / $I:(DE-82)080011_20140620$},
pnm = {113 - Methods and Concepts for Material Development
(POF3-113)},
pid = {G:(DE-HGF)POF3-113},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000348686200018},
doi = {10.1016/j.jeurceramsoc.2014.11.010},
url = {https://juser.fz-juelich.de/record/255479},
}