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000255535 245__ $$aOn the True Indium Content of In-Filled Skutterudites
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000255535 520__ $$aHigh-purity InxCo4Sb12 (nominal composition x = 0.12, 0.15, 0.18, 0.20) was prepared by a two-step method separating the CoSb3 formation from the topotactic filler insertion. The high purity of the compounds allowed studying the transport properties without bias from side phases. In0.160(2)Co4Sb12 (nominally In0.18Co4Sb12) revealed a zT ≈ 1 at 420°C. The linear correlation between the true In occupancy and lattice parameter a indicates the true In filling and allows predicting the filler content of AxCo4Sb12.
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000255535 7001_ $$0P:(DE-HGF)0$$aHeinrich, Christophe P.$$b1
000255535 7001_ $$0P:(DE-HGF)0$$aSchmitz, Andreas$$b2
000255535 7001_ $$0P:(DE-HGF)0$$ade Boor, Johannes$$b3
000255535 7001_ $$0P:(DE-HGF)0$$aLeidich, Patrick$$b4
000255535 7001_ $$0P:(DE-Juel1)144500$$aKlobes, Benedikt$$b5
000255535 7001_ $$0P:(DE-HGF)0$$aMüller, Wolf Eckhard$$b6$$eCorresponding author
000255535 7001_ $$0P:(DE-HGF)0$$aTremel, Wolfgang$$b7
000255535 7001_ $$0P:(DE-Juel1)130706$$aHermann, Raphael$$b8
000255535 773__ $$0PERI:(DE-600)1484438-2$$a10.1021/acs.inorgchem.5b00799$$gVol. 54, no. 16, p. 7818 - 7827$$n16$$p7818 - 7827$$tInorganic chemistry$$v54$$x1520-510X$$y2015
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