TY  - JOUR
AU  - Visnow, Eduard
AU  - Heinrich, Christophe P.
AU  - Schmitz, Andreas
AU  - de Boor, Johannes
AU  - Leidich, Patrick
AU  - Klobes, Benedikt
AU  - Müller, Wolf Eckhard
AU  - Tremel, Wolfgang
AU  - Hermann, Raphael
TI  - On the True Indium Content of In-Filled Skutterudites
JO  - Inorganic chemistry
VL  - 54
IS  - 16
SN  - 1520-510X
CY  - Washington, DC
PB  - American Chemical Society
M1  - FZJ-2015-05696
SP  - 7818 - 7827
PY  - 2015
AB  - High-purity InxCo4Sb12 (nominal composition x = 0.12, 0.15, 0.18, 0.20) was prepared by a two-step method separating the CoSb3 formation from the topotactic filler insertion. The high purity of the compounds allowed studying the transport properties without bias from side phases. In0.160(2)Co4Sb12 (nominally In0.18Co4Sb12) revealed a zT ≈ 1 at 420°C. The linear correlation between the true In occupancy and lattice parameter a indicates the true In filling and allows predicting the filler content of AxCo4Sb12.
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000359824400016
C6  - pmid:26213290
DO  - DOI:10.1021/acs.inorgchem.5b00799
UR  - https://juser.fz-juelich.de/record/255535
ER  -