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@ARTICLE{Gupta:255635,
author = {Gupta, Sudipta and Stellbrink, Jörg and Zaccarelli,
Emanuela and Likos, Christos N. and Camargo, Manuel and
Holmqvist, Peter and Allgaier, J. and Willner, Lutz and
Richter, Dieter},
title = {{V}alidity of the {S}tokes-{E}instein {R}elation in {S}oft
{C}olloids up to the {G}lass {T}ransition},
journal = {Physical review letters},
volume = {115},
number = {12},
issn = {1079-7114},
address = {College Park, Md.},
publisher = {APS},
reportid = {FZJ-2015-05770},
pages = {128302},
year = {2015},
abstract = {We investigate the dynamics of kinetically frozen block
copolymer micelles of different softness across a wide range
of particle concentrations, from the fluid to the onset of
glassy behavior, through a combination of rheology, dynamic
light scattering, and pulsed field gradient NMR
spectroscopy. We additionally perform Brownian dynamics
simulations based on an ultrasoft coarse-grained potential,
which are found to be in quantitative agreement with
experiments, capturing even the very details of dynamic
structure factors S(Q,t) on approaching the glass
transition. We provide evidence that for these systems the
Stokes-Einstein relation holds up to the glass transition;
given that it is violated for dense suspensions of hard
colloids, our findings suggest that its validity is an
intriguing signature of ultrasoft interactions.},
cin = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
(München) ; JCNS-FRM-II / Neutronenstreuung ; JCNS-1 /
ICS-1},
ddc = {550},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-1-20110106 / I:(DE-Juel1)ICS-1-20110106},
pnm = {551 - Functional Macromolecules and Complexes (POF3-551) /
6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
/ 6215 - Soft Matter, Health and Life Sciences (POF3-621)},
pid = {G:(DE-HGF)POF3-551 / G:(DE-HGF)POF3-6G4 /
G:(DE-HGF)POF3-6215},
experiment = {EXP:(DE-MLZ)NOSPEC-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000361316500017},
pubmed = {pmid:26431020},
doi = {10.1103/PhysRevLett.115.128302},
url = {https://juser.fz-juelich.de/record/255635},
}