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@ARTICLE{Feyer:255820,
      author       = {Feyer, V. and Graus, M. and Nigge, P. and Zamborlini, G.
                      and Acres, R. G. and Schöll, A. and Reinert, F. and
                      Schneider, C. M.},
      title        = {{T}he geometric and electronic structure of {TCNQ} and
                      {TCNQ}+{M}n on {A}g(001) and {C}u(001) surfaces},
      journal      = {Journal of electron spectroscopy and related phenomena},
      volume       = {204},
      issn         = {0368-2048},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2015-05931},
      pages        = {125 - 131},
      year         = {2015},
      abstract     = {Copper and silver surfaces can be used as model systems to
                      study structure formation and interfacial bonding upon
                      adsorption of organic molecules. We have investigated the
                      geometric and electronic structure of ordered monolayers of
                      TCNQ on Cu(0 0 1) and Ag(0 0 1) and of TCNQ+Mn on Ag(0 0 1)
                      surfaces by LEED and photoelectron momentum microscopy.
                      While TCNQ forms an incommensurable superstructure on Cu(0 0
                      1), two coverage-dependant, commensurable superstructures
                      are established on Ag(0 0 1). Subsequent adsorption of Mn on
                      top of TCNQ/Ag(0 0 1) results in the formation of a
                      long-range ordered mixed metal–organic superstructure,
                      which is also commensurable with the Ag(0 0 1) substrate.
                      The photoelectron spectroscopy (PES) data shows a filling of
                      the TCNQ LUMO by charge transfer from the substrate for all
                      investigated interfaces and the coadsorption of Mn leads to
                      an energy shift of the TCNQ HOMO and LUMO of 230 meV with
                      respect to TCNQ/Ag(0 0 1). The characteristic
                      angle-dependent intensity pattern of the TCNQ LUMO in PES
                      was utilized to investigate the azimuthal orientation of the
                      molecules in the respective unit cells. The angle-resolved
                      PES data was further analyzed to identify lateral band
                      dispersion effects in the adsorbate layers, but no
                      significant dispersion was observed.},
      cin          = {PGI-6},
      ddc          = {620},
      cid          = {I:(DE-Juel1)PGI-6-20110106},
      pnm          = {522 - Controlling Spin-Based Phenomena (POF3-522)},
      pid          = {G:(DE-HGF)POF3-522},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000363078400015},
      doi          = {10.1016/j.elspec.2015.02.010},
      url          = {https://juser.fz-juelich.de/record/255820},
}