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@ARTICLE{Hinterstein:256251,
author = {Hinterstein, M. and Hoelzel, M. and Rouquette, J. and
Haines, J. and Glaum, J. and Kungl, H. and Hoffman, M.},
title = {{I}nterplay of strain mechanisms in morphotropic
piezoceramics},
journal = {Acta materialia},
volume = {94},
issn = {1359-6454},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {FZJ-2015-06218},
pages = {319 - 327},
year = {2015},
abstract = {A large number of transducers, ultrasonic motors or
actuators are based on lead zirconate titanate (PZT)
piezoceramics, with compositions near the morphotropic phase
boundary (MPB) where the relevant material properties
approach their maximum. Since the best piezoelectric
properties, in particular the highest recoverable strains,
are observed for these MPB compositions with phase
coexistences, a separate analysis of each phase is
mandatory. Here we present a sophisticated method to
correlate the macroscopic strain observations to mechanisms
on the atomic scale. The technique allows a quantification
of all contributing strain mechanisms such as lattice
strain, domain switching and phase transition for each
phase. These results indicate that the major strain
contribution is of structural instead of microstructural
origin and the electric field induced phase transition
occurs through polarisation rotation. Such a mechanism could
be generalised in other MPB piezoceramics and will be useful
to design and optimise the next generation of high
performance piezoelectric materials.},
cin = {IEK-9},
ddc = {670},
cid = {I:(DE-Juel1)IEK-9-20110218},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000357143500029},
doi = {10.1016/j.actamat.2015.04.017},
url = {https://juser.fz-juelich.de/record/256251},
}