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@ARTICLE{Bnyai:256282,
      author       = {Bányai, István and Lakatos, István and Nagy, Zoltán and
                      Vass, Szabolcs and Meier, G.},
      title        = {{H}ydrated micellar structure of ethoxylated nonyl phenols
                      from {PGSE} {NMR}},
      journal      = {Bulletin of the Chemical Society of Japan},
      volume       = {90},
      number       = {7},
      issn         = {1348-0634},
      address      = {Tokyo},
      publisher    = {Soc.},
      reportid     = {FZJ-2015-06246},
      pages        = {854 - 862},
      year         = {2017},
      abstract     = {Solvent self-diffusion coefficients D∗w and Dw are
                      respectively determined by PGSE NMR in the bulk solvent and
                      in suitably prepared aqueous micellar solutions of a series
                      of commercial ethoxylated nonyl phenols (ENPs) at 298 and
                      317 K. The capability of ENP micelles for obstructing the
                      free diffusion of solvent molecules is characterized by the
                      obstruction ratio K=Dw/D∗w, which turns out to depend
                      merely on the volume fraction of EO units
                      present—regardless of significant changes in solute
                      concentration, distribution of EO chain length, micellar
                      aggregation number and temperature. The experiments are
                      interpreted in terms of a renewed analytical model of ENP
                      micellar structure, based on Tanford’s concept of
                      hydrodynamic particle. The results from model fitting return
                      the characteristic sizes of ENP monomers, support the
                      ellipsoid shape of the micelles, indicate a stable EO shell,
                      follow the trend in the variation of hydration number vs.
                      the chain length predicted by thermal analysis in PEO
                      solutions.},
      cin          = {ICS-3},
      ddc          = {540},
      cid          = {I:(DE-Juel1)ICS-3-20110106},
      pnm          = {551 - Functional Macromolecules and Complexes (POF3-551)},
      pid          = {G:(DE-HGF)POF3-551},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000404857900001},
      doi          = {10.1246/bcsj.20170050},
      url          = {https://juser.fz-juelich.de/record/256282},
}