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001     256324
005     20240709081956.0
037 _ _ |a FZJ-2015-06285
041 _ _ |a English
100 1 _ |a Guin, Marie
|0 P:(DE-Juel1)158083
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|e Corresponding author
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111 2 _ |a Materials Science & Technology 2015
|c Columbus, Ohio
|d 2015-10-04 - 2015-10-08
|w USA
245 _ _ |a Development of solid state electrolytes for lithium and sodium ion batteries
260 _ _ |c 2015
336 7 _ |a Conference Presentation
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336 7 _ |a Conference Paper
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336 7 _ |a Other
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336 7 _ |a LECTURE_SPEECH
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336 7 _ |a INPROCEEDINGS
|2 BibTeX
520 _ _ |a NASICON materials of the general formula AMM’(SiO4)x(PO4)3-x (A = Li or Na, M and M’ = Al, Ti, Sc or Zr) are investigated because they are promising solid-state electrolytes for Li- or Na-ion batteries. A novel sol-gel method was developed to prepare Li1.5Al0.5Ti1.5(PO4)3 in kg-level and at low cost with high phase purity. The lithium conductivity of the samples reached 5 × 10-4 S/cm at room temperature. Na3.4Sc2(SiO4)0.4(PO4)2.6 powders were synthesized via solid state reaction and the sodium conductivity of the samples at room temperature was 8 × 10-4 S/cm. These values place our materials among the best NASICON conductive materials reported to date. The impact of water on the measured conductivities and activation energies was also investigated for different NASICON compositions, as well as the stability of these electrolytes against electrode materials.
536 _ _ |a 131 - Electrochemical Storage (POF3-131)
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536 _ _ |0 G:(DE-Juel1)HITEC-20170406
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|c HITEC-20170406
|a HITEC - Helmholtz Interdisciplinary Doctoral Training in Energy and Climate Research (HITEC) (HITEC-20170406)
700 1 _ |a Ma, Qianli
|0 P:(DE-Juel1)129628
|b 1
|u fzj
700 1 _ |a Xu, Qi
|0 P:(DE-Juel1)164176
|b 2
700 1 _ |a Dashjav, Enkhtsetseg
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700 1 _ |a Sierau, Jennyfer
|0 P:(DE-Juel1)161419
|b 4
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700 1 _ |a Tietz, Frank
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|b 5
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700 1 _ |a Guillon, Olivier
|0 P:(DE-Juel1)161591
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909 C O |o oai:juser.fz-juelich.de:256324
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910 1 _ |a Forschungszentrum Jülich GmbH
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913 1 _ |a DE-HGF
|l Speicher und vernetzte Infrastrukturen
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|0 G:(DE-HGF)POF3-131
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|v Electrochemical Storage
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914 1 _ |y 2015
920 _ _ |l yes
920 1 _ |0 I:(DE-Juel1)IEK-1-20101013
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